ArticleJournal of the American Chemical Society2024
Mechanically Triggered Bright Chemiluminescence from Polymers by Exploiting a Synergy between Masked 2-Furylcarbinol Mechanophores and 1,2-Dioxetane Chemiluminophores.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed.
- Force-Induced Control of Circularly Polarized Luminescence With Rotaxane Architecture.Angewandte Chemie (International ed. in English) · 2026Article
- Precise Mechanochemical Scission of DNA Guided by Secondary Structures.Journal of the American Chemical Society · 2026Article
- Diverse reactivity of maleimides in polymer science and beyond.Polymer international · 2025Article
- Chemiluminescent 2-Coumaranones: Synthesis, Luminescence Mechanism, and Emerging Applications.Molecules (Basel, Switzerland) · 2025Review
- Mechanoluminescence from Organic-Inorganic Metal Halide Perovskite Derivative.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- The Role of Torsion on the Force-Coupled Reactivity of a Fluorenyl Naphthopyran Mechanophore.Journal of the American Chemical Society · 2025Article
- Molecular Engineering of Direct Activated NIR-II Chemiluminescence Platform for In Vivo Chemiluminescence-fluorescence Duplex Imaging.Nature communications · 2025Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Mechanoluminescence, or the generation of light from materials under external force, is a powerful tool for biology and materials science. However, direct mechanoluminescence from polymers remains limited. Here, we report a novel design strategy for mechanoluminescent polymers that leverages the synergy between a masked 2-furylcarbinol mechanophore for mechanically triggered release and an adamantylidene-phenoxy-1,2-dioxetane chemiluminophore payload. Ultrasound-induced mechanochemical activation of polymers, in both organic and aqueous solutions, triggers a cascade reaction that ultimately results in bright green light emission. This novel strategy capitalizes on the modularity of the masked 2-furylcarbinol mechanophore system in combination with advances in the design of exceptionally bright and highly tunable adamantylidene-1,2-dioxetane chemiluminophores. We anticipate that this chemistry will enable diverse applications in optoelectronics, sensing, bioimaging, optogenetics, and many other areas.
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Registered trials
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