ArticleInorganic chemistry2024
Mechanochemical Synthesis of a Sodium Anion Complex [Na
Article in Inorganic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Ligand- and alkali metal identity-effects in ligand-inducedChemical science · 2026Article
- Reactivity of a Sodium Anion with Alkenes: 1-Electron vs 2-Electron Reductions.Inorganic chemistry · 2025Article
- Meeting the UN Sustainable Development Goals with Mechanochemistry.Angewandte Chemie (International ed. in English) · 2024Review
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Group 1 metal molecular chemistry is dominated by a +1 oxidation state, while a 0 oxidation state is widespread in the metals. A more exotic, yet still available, oxidation state of group 1 metal is -1, i.e., alkalide. Reported as early as the 1970s, the alkalides appear in every modern inorganic chemistry textbook as an iconic chemical curiosity, yet their reactivity remains unexplored. This is due to their synthetic hurdles. In this work, we report the first facile synthesis of the archetypical alkalide complex, [Na
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