A Nickel/Organoboron-Catalyzed Coupling of Aryl Bromides with Sodium Sulfinates: The Synthesis of Sulfones under Visible Light.

Siyi Ding, Weina Tian, Qiaohuan Lv, Zongcheng Miao, Liang Xu

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Article in Molecules (Basel, Switzerland), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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5 · Who and what money

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5 authors.

Siyi DingSchool of Electronic Information, Technological Institute of Materials & Energy Science (TIMES), Xi'an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, Xijing University, Xi'an 710123, China.ORCID 0000-0001-5446-0254

Weina TianSchool of Chemistry and Chemical Engineering, State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi 832003, China.

Qiaohuan LvSchool of Electronic Information, Technological Institute of Materials & Energy Science (TIMES), Xi'an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, Xijing University, Xi'an 710123, China.

Zongcheng MiaoSchool of Electronic Information, Technological Institute of Materials & Energy Science (TIMES), Xi'an Key Laboratory of Advanced Photo-Electronics Materials and Energy Conversion Device, Xijing University, Xi'an 710123, China.

Liang XuSchool of Chemistry and Chemical Engineering, State Key Laboratory Incubation Base for Green Processing of Chemical Engineering, Shihezi University, Shihezi 832003, China.ORCID 0000-0002-7939-8108

Funding

Natural Science Basic Research Plan in Shaanxi Province of China 2022JQ-127Natural Science Foundation of Shaanxi Province 2022JM-063Science Research Foundation of Xijing University XJ22T02Xijing University Special Fund for Talent Research in Special Zone XJ22T03

6 · The paper itself

Abstract

An efficient cross-coupling of aryl bromides with sodium sulfinates, using an organoboron photocatalyst with nickel, is described herein. Under the irradiation of white light, this dually catalytic system enables the synthesis of a series of sulfone compounds in moderate to good yields. A broad range of functional groups and heteroaromatic compounds is tolerated under these reaction conditions. The use of an organoboron photocatalyst highlights a sustainable alternative to iridium or ruthenium complexes. These findings contribute to the field of photochemistry and provide a greener approach to sulfone synthesis.

Indexed as

dually catalytic systemorganoboron photocatalystsodium sulfinatessulfone compounds

Identifiers

PMID39064996

DOI10.3390/molecules29143418

PMCPMC11280069

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