Evidence map›Paper›PMID 39063233›Full record

ArticleInternational journal of molecular sciences2024

Theoretical and Experimental Study on Carbodiimide Formation.

Marcell Dániel Csécsi, Virág Kondor, Edina Reizer, Renáta Zsanett Boros, Péter Tóth, László Farkas, Béla Fiser, Zoltán Mucsi, Miklós Nagy, Béla Viskolcz

Abstract read
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In one paragraph

Article in International journal of molecular sciences, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Marcell Dániel CsécsiInstitute of Chemistry, University of Miskolc, H-3515 Miskolc, Hungary.ORCID 0009-0009-8150-8650
Virág KondorInstitute of Chemistry, University of Miskolc, H-3515 Miskolc, Hungary.
Edina ReizerInstitute of Chemistry, University of Miskolc, H-3515 Miskolc, Hungary.
Renáta Zsanett BorosBorsodChem Ltd., Bolyai tér 1, H-3700 Kazincbarcika, Hungary.
Péter TóthBorsodChem Ltd., Bolyai tér 1, H-3700 Kazincbarcika, Hungary.
László FarkasBorsodChem Ltd., Bolyai tér 1, H-3700 Kazincbarcika, Hungary.ORCID 0000-0003-4328-486X
Béla FiserInstitute of Chemistry, University of Miskolc, H-3515 Miskolc, Hungary.ORCID 0000-0003-0603-4626
Zoltán MucsiInstitute of Chemistry, University of Miskolc, H-3515 Miskolc, Hungary.
Miklós NagyInstitute of Chemistry, University of Miskolc, H-3515 Miskolc, Hungary.ORCID 0000-0002-3484-2244
Béla ViskolczInstitute of Chemistry, University of Miskolc, H-3515 Miskolc, Hungary.ORCID 0000-0002-0777-9569

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Carbodiimides are important crosslinkers in organic synthesis and are used in the isocyanate industry as modifier additives. Therefore, the understanding of their formation is of high importance. In this work, we present a theoretical B3LYP/6-31G(d) and SMD solvent model and experimental investigation of the formation of diphenylcarbodiimide (CDI) from phenyl isocyanate using a phosphorus-based catalyst (MPPO) in ortho-dichlorobenzene (ODCB) solvent. Kinetic experiments were based on the volumetric quantitation of CO

Indexed as

CarbodiimidesIsocyanatesKineticsTemperatureThermodynamicsCarbodiimidesIsocyanatesactivation energycarbodiimideDFTgas volumetryisocyanateorganocatalysisreaction kinetics

Identifiers

PMID39063233
PMCPMC11276972

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.