Evidence map›Paper›PMID 39060469›Full record

ArticleNature materials2024

Non-equilibrium transport in polymer mixed ionic-electronic conductors at ultrahigh charge densities.

Dionisius H L Tjhe, Xinglong Ren, Ian E Jacobs, Gabriele D'Avino, Tarig B E Mustafa, Thomas G Marsh, Lu Zhang, Yao Fu, Ahmed E Mansour, Andreas Opitz and 15 more

Abstract read
In one paragraph

Article in Nature materials, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Review
  5. Article
  6. Nonequilibrium relaxation exponentially delays the onset of quantum diffusion.Proceedings of the National Academy of Sciences of the United States of America · 2025
    Article
  7. Article
  8. Review
  9. Article
  10. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

25 authors.

Dionisius H L Tjhe *Cavendish Laboratory, University of Cambridge, Cambridge, UK.ORCID http://orcid.org/0000-0003-3994-1919
Xinglong Ren *Cavendish Laboratory, University of Cambridge, Cambridge, UK. xr216@cam.ac.uk.ORCID http://orcid.org/0000-0001-9824-5767
Ian E Jacobs *Cavendish Laboratory, University of Cambridge, Cambridge, UK. ij255@cam.ac.uk.ORCID http://orcid.org/0000-0002-1535-4608
Gabriele D'Avino *Grenoble Alpes University, CNRS, Grenoble INP, Institut Néel, Grenoble, France. gabriele.davino@neel.cnrs.fr.ORCID http://orcid.org/0000-0002-5897-2924
Tarig B E MustafaCavendish Laboratory, University of Cambridge, Cambridge, UK.
Thomas G MarshCavendish Laboratory, University of Cambridge, Cambridge, UK.
Lu ZhangCavendish Laboratory, University of Cambridge, Cambridge, UK.
Yao FuDepartment of Chemistry, University of Cambridge, Cambridge, UK.
Ahmed E MansourInstitut für Physik and Center for the Science of Materials Berlin, Humboldt-Universität zu Berlin, Berlin, Germany.
Andreas OpitzInstitut für Physik and Center for the Science of Materials Berlin, Humboldt-Universität zu Berlin, Berlin, Germany.ORCID http://orcid.org/0000-0002-3214-8398
Yuxuan HuangCavendish Laboratory, University of Cambridge, Cambridge, UK.ORCID http://orcid.org/0000-0002-7249-8480
Wenjin ZhuCavendish Laboratory, University of Cambridge, Cambridge, UK.
Ahmet Hamdi UnalCavendish Laboratory, University of Cambridge, Cambridge, UK.ORCID http://orcid.org/0000-0002-1438-6878
Sebastiaan HoekCavendish Laboratory, University of Cambridge, Cambridge, UK.ORCID http://orcid.org/0009-0009-8534-7540
Vincent LemaurLaboratory for Chemistry of Novel Materials, University of Mons, Mons, Belgium.ORCID http://orcid.org/0000-0001-8601-286X
Claudio QuartiLaboratory for Chemistry of Novel Materials, University of Mons, Mons, Belgium.ORCID http://orcid.org/0000-0002-5488-1216
Qiao HeDepartment of Chemistry and Centre for Processable Electronics, Imperial College London, London, UK.ORCID http://orcid.org/0000-0002-9383-9387
Jin-Kyun LeeDepartment of Polymer Science and Engineering, Inha University, Incheon, South Korea.
Iain McCullochDepartment of Chemistry, University of Oxford, Oxford, UK.ORCID http://orcid.org/0000-0002-6340-7217
Martin HeeneyDepartment of Chemistry and Centre for Processable Electronics, Imperial College London, London, UK.ORCID http://orcid.org/0000-0001-6879-5020
Norbert KochInstitut für Physik and Center for the Science of Materials Berlin, Humboldt-Universität zu Berlin, Berlin, Germany.ORCID http://orcid.org/0000-0002-6042-6447
Clare P GreyDepartment of Chemistry, University of Cambridge, Cambridge, UK.ORCID http://orcid.org/0000-0002-6867-6715
David BeljonneLaboratory for Chemistry of Novel Materials, University of Mons, Mons, Belgium.ORCID http://orcid.org/0000-0001-5082-9990
Simone FratiniGrenoble Alpes University, CNRS, Grenoble INP, Institut Néel, Grenoble, France.ORCID http://orcid.org/0000-0002-4750-3241
Henning SirringhausCavendish Laboratory, University of Cambridge, Cambridge, UK. hs220@cam.ac.uk.ORCID http://orcid.org/0000-0001-9827-6061

Funding

Agence Nationale de la Recherche (French National Research Agency) ANR-21-CE24-0004-01EC | EC Seventh Framework Programm | FP7 Ideas: European Research Council (FP7-IDEAS-ERC - Specific Programme: "Ideas" Implementing the Seventh Framework Programme of the European Community for Research, Technological Development and Demonstration Activities (2007 to 2013)) 101020872EC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council) 101020872RCUK | Engineering and Physical Sciences Research Council (EPSRC) EP/W017091
6 · The paper itself

Abstract

Conducting polymers are mixed ionic-electronic conductors that are emerging candidates for neuromorphic computing, bioelectronics and thermoelectrics. However, fundamental aspects of their many-body correlated electron-ion transport physics remain poorly understood. Here we show that in p-type organic electrochemical transistors it is possible to remove all of the electrons from the valence band and even access deeper bands without degradation. By adding a second, field-effect gate electrode, additional electrons or holes can be injected at set doping states. Under conditions where the counterions are unable to equilibrate in response to field-induced changes in the electronic carrier density, we observe surprising, non-equilibrium transport signatures that provide unique insights into the interaction-driven formation of a frozen, soft Coulomb gap in the density of states. Our work identifies new strategies for substantially enhancing the transport properties of conducting polymers by exploiting non-equilibrium states in the coupled system of electronic charges and counterions.

Identifiers

PMID39060469
PMCPMC11599050

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.