ArticleNature synthesis2023
A general method for metallocluster site-differentiation.
Article in Nature synthesis, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
6 citing papers in PubMed.
- Article
- Article
- Nitrogen Subvalency in a Four-Member Redox Series of Iron-Sulfur Cluster Imido Complexes.Journal of the American Chemical Society · 2025Article
- Stepwise and reversible assembly of [2Fe-2S] rhombs to [8Fe-8S] clusters and their topological interconversions.Nature chemistry · 2025Article
- Distinct Valence States of the [4Fe4S] Cluster Revealed in the Hydrogenase CrHydA1.Angewandte Chemie (International ed. in English) · 2025Article
- An Iron-Sulfur Cluster with a Highly Pyramidalized Three-Coordinate Iron Center and a Negligible Affinity for Dinitrogen.Journal of the American Chemical Society · 2023Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
The deployment of metalloclusters in applications such as catalysis and materials synthesis requires robust methods for site-differentiation: the conversion of clusters with symmetric ligand spheres to those with unsymmetrical ligand spheres. However, imparting precise patterns of site-differentiation is challenging because, compared with mononuclear complexes, the ligands bound to clusters exert limited spatial and electronic influence on one another. Here, we report a method that employs sterically encumbering ligands to bind to only a subset of a cluster's coordination sites. Specifically, we show that homoleptic, phosphine-ligated Fe-S clusters undergo ligand substitution with
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Registered trials
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