ArticleJACS Au2024
Polyoxometalate Ligands Reveal Different Coordination Chemistries Among Lanthanides and Heavy Actinides.
Article in JACS Au, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Tuning Uranium Redox Chemistry in Asymmetric Polyoxometalate Complexes: Access to U(IV), U(V), and Transient U(VI).Inorganic chemistry · 2026Article
- TGMin-MLP: a new package for predicting the structures of the mono- and poly-nuclear clusters by the machine learning method.Journal of molecular modeling · 2026Article
- Lanthanide-Centered Polyoxoalkoxide Complexes Provide a Platform for Systematic Room- and Variable-Temperature Nuclear Magnetic Resonance Studies.Inorganic chemistry · 2026Article
- Electronic energy levels and optical spectra of trivalent lanthanide ions in water - Ce(III), Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), and Yb(III).Nature communications · 2025Article
- Isolation of Ce(iv) centered polyoxoalkoxide sandwich-type complexes allows comparison of metal-oxygen bond covalency.Chemical science · 2025Article
- Determining molecular structure, coordination geometry, and molecular symmetry using a continuous symmetry operation measure software.Nature communications · 2025Article
- Delineating the Effects of Counterions on the Structural and Vibrational Properties of U(IV) Lindqvist Polyoxometalate Complexes.Inorganic chemistry · 2025Article
- Probing the Framework Metal Dependent Properties of Actinide-Centered Polyoxoalkoxide Sandwich-Type Complexes.Inorganic chemistry · 2025Article
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Authors and funding
2 authors.
Funding
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Abstract
Experimental studies involving actinide compounds are inherently limited in scope due to the radioactive nature of these elements and the scarcity and cost of their research isotopes. Now, ∼80 years after the introduction of the actinide concept by Glenn Seaborg, we still only have a limited understanding of the coordination chemistry of f-block metals when compared to more common elements such as the s-, p-, and d-blocks. This is particularly true for transplutonium actinides (Am, Cm, Bk, etc.) whose chemistry is often considered similar to trivalent lanthanides-mainly because of the lack of experimental data. We here report a metal-ligand system for which lanthanide and heavy actinide coordination compounds can be synthesized efficiently (i.e., requiring only a few micrograms) under identical conditions. Seventeen single crystal XRD structures of trivalent f-elements complexed to the polyoxometalate (POM) PW
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