ArticleNature communications2024
Enabling long-distance hydrogen spillover in nonreducible metal-organic frameworks for catalytic reaction.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Photocontrolled nanosystem potentiates photo-chemoimmunotherapy against TNBC by integrating apoptosis/ferroptosis/ pyroptosis and STING activation.Materials today. Bio · 2026Article
- Decoupled Catalysis in Lithium-Oxygen Batteries: Directed Oxygen-Species Spillover Between Dual Single-Atoms to Circumvent Linear Scaling Limit.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Sustainable Synthesis of Ammonium Nitrate From Air and Water via Tandem Plasma-Electrolyzer System.Angewandte Chemie (International ed. in English) · 2026Article
- Catalytic Upcycling of Barrier Plastic Films by Selective Deoxygenation of Ethylene Vinyl Alcohol over Pd/MoOACS sustainable chemistry & engineering · 2026Article
- Mechanism study of hollow-structured MOFs improving catalytic performance.Nature communications · 2026Article
- Conjugation Lock-In Reinforced Sulfur-Heteropolycyclic Covalent Organic Frameworks with Asymmetric Electron Distribution for Photocatalytic Aerobic Oxidation Reactions.Journal of the American Chemical Society · 2026Article
- Beyond Sabatier: Multiplicate Spillover Phenomena for Manipulating Catalytic Dynamics in Various Electrocatalysis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- [H]-mediated enhancement of the Fenton reaction over a Pd/UiO-66(Zr)-FTurkish journal of chemistry · 2026Article
- UiO-type metal - organic frameworks as a platform for hydrogen storage studies.Science and technology of advanced materials · 2026Review
- Water adlayers bridging metal spillover to boost catalytic activity.Nature communications · 2025Article
- Homologous heteropolyaromatic covalent organic frameworks for enhancing photocatalytic hydrogen peroxide production and aerobic oxidation.Nature communications · 2025Article
- Fabrication of FeBMC chemistry · 2025Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Hydrogen spillover is an extraordinary effect in heterogeneous catalysis and hydrogen storage, which refers to the surface migration of metal particle-activated hydrogen atoms over the solid supports. Historical studies on this phenomenon have mostly been limited to reducible metal oxides where the long-distance proton-electron coupled migration mechanism has been established, yet the key question remains on how to surmount short-distance and defect-dependent hydrogen migration on nonreducible supports. By demerging hydrogen migration and hydrogenation reaction, here we demonstrate that the hydrogen spillover in nonreducible metal-organic frameworks (MOFs) can be finely modulated by the ligand functional groups or embedded water molecules, enabling significant long-distance (exceed 50 nm) movement of activated hydrogen. Furthermore, using sandwich nanostructured MOFs@Pt@MOFs as catalysts, we achieve highly selective hydrogenation of N-heteroarenes via controllable hydrogen spillover from Pt to MOFs-shell. We anticipate that this work will enhance the understanding of hydrogen spillover and shed light on de novo design of MOFs supported catalysts for many important reactions involving hydrogen.
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Registered trials
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