ArticleJournal of the American Chemical Society2024
The Delayed Box: Biphenyl Bisimide Cyclophane, a Supramolecular Nano-environment for the Efficient Generation of Delayed Fluorescence.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Planar Chiral Carbazole-Naphthalene Bisimide Hetero-Cyclophane for Circularly Polarized Delayed Fluorescence.Angewandte Chemie (International ed. in English) · 2026Article
- Inclusion co-crystals based on Tröger's base molecular box for thermally activated delayed fluorescence.Nature communications · 2026Article
- A state-switchable TADF macrocycle for multi-analyte sensing and hydrogen gas-driven emission enhancement.Communications chemistry · 2026Article
- Guest-Induced Activation of Multicolor Photoluminescence in Naphthalene Bisimide Liquid Crystals.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Chiral inheritance effect in the reactive cystine-based coassembly system.Nature communications · 2026Article
- Non-macrocyclic molecular design enables cavity-adaptive cocrystals with high elasticity and low-threshold lasing.Nature communications · 2026Article
- Interlocked Rotaxane Enables TADF with Distinct Excited-State Structural Relaxation.Journal of the American Chemical Society · 2026Article
- Multicolor Luminescent Supramolecular Bidirectional Shuttles Driven by Light.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Activating delayed fluorescence emission in a dilute solution via a non-covalent approach is a formidable challenge. In this report, we propose a strategy for efficient delayed fluorescence generation in dilute solution using a non-covalent approach via supramolecularly engineered cyclophane-based nanoenvironments that provide sufficient binding strength to π-conjugated guests and that can stabilize triplet excitons by reducing vibrational dissipation and lowering the singlet-triplet energy gap for efficient delayed fluorescence emission. Toward this goal, a novel biphenyl bisimide-derived cyclophane is introduced as an electron-deficient and efficient triplet-generating host. Upon encapsulation of various carbazole-derived guests inside the nanocavity of this cyclophane, emissive charge transfer (CT) states close to the triplet energy level of the biphenyl bisimide are generated. The experimental results of host-guest studies manifest high association constants up to 10
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.