ArticleNature materials2024
Enhanced elastic stability of a topologically disordered crystalline metal-organic framework.
Article in Nature materials, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
12 citing papers in PubMed.
- Unlocking the door for synergizing expansion-capacity in Si anodes: breathable flexible MOFs.Chemical science · 2026Review
- Carboxylate-Ligand-Based Coordination Polymers and Metal Complexes: From Structural Diversity and Supramolecular Descriptors to Function-Oriented Design.Molecules (Basel, Switzerland) · 2026Review
- Hotspot to Homogeneous: Amorphous Interfacial Current Redistribution Enables Stable Solid-State Lithium-Metal Batteries.Nano-micro letters · 2026Article
- Evaluating mechanical property prediction across material classes using molecular dynamics simulations with universal machine-learned interatomic potentials.Communications chemistry · 2026Article
- Computational Modeling of Reticular Materials: The Past, the Present, and the Future.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Elastic Properties of Defective 2D Polymers from Regression Driven Coarse-Graining.Journal of chemical theory and computation · 2025Article
- Isoreticular moiré metal-organic frameworks with quasiperiodicity.Nature communications · 2025Article
- Inverse Design of Highly Deformable Mechanical Metamaterial Based on Partitional Semi-Random Optimization.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Decoupled MOF Breathing: Pressure-Induced Reversal of Correlation Between Orthogonal Motions in a Diamondoid Framework.Angewandte Chemie (International ed. in English) · 2025Article
- A lanthanide MOF with nanostructured node disorder.Nature communications · 2025Article
- Article
- Harnessing disorder to advance metal-organic framework resilience.Nature materials · 2024Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
7 authors.
Funding
Abstract
By virtue of their open network structures and low densities, metal-organic frameworks (MOFs) are soft materials that exhibit elastic instabilities at low applied stresses. The conventional strategy for improving elastic stability is to increase the connectivity of the underlying MOF network, which necessarily increases the material density and reduces the porosity. Here we demonstrate an alternative paradigm, whereby elastic stability is enhanced in a MOF with an aperiodic network topology. We use a combination of variable-pressure single-crystal X-ray diffraction measurements and coarse-grained lattice-dynamical calculations to interrogate the high-pressure behaviour of the topologically aperiodic system TRUMOF-1, which we compare against that of its ordered congener MOF-5. We show that the topology of the former quenches the elastic instability responsible for pressure-induced framework collapse in the latter, much as irregularity in the shapes and sizes of stones acts to prevent cooperative mechanical failure in drystone walls. Our results establish aperiodicity as a counter-intuitive design motif in engineering the mechanical properties of framework structures that is relevant to MOFs and larger-scale architectures alike.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.