ArticleJournal of the American Chemical Society2024
GaSI: A Wide-Gap Non-centrosymmetric Helical Crystal.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
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Who cites it
4 citing papers in PubMed.
- Dimensionally Resolved Nanostructures of an Atomically Precise and Optically Active 1D van der Waals Helix.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Facet-Specific Liquid-Phase Exfoliation of an Ionic 1D Crystal, (NbSeACS materials Au · 2026Article
- Phosphorus-lithium double-helix nanoribbons.Science advances · 2025Article
- Low-Dimensional Semiconducting Silver (Germanium, Tin) Polyphosphides - Incommensurately Modulated Derivates of the HgPbPInorganic chemistry · 2025Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The complex non-centrosymmetric and chiral nature of helical structures endow materials that possess such motifs with unusual properties. However, despite their ubiquity in biological and organic systems, there is a severe lack of inorganic crystals that display helicity in extended lattices, where these unusual properties are expected to be most pronounced. Here, we report a new inorganic helical structure, gallium sulfur iodide (GaSI), within the exfoliable class of III-VI-VII (1:1:1) one-dimensional (1D) van der Waals (vdW) crystals. Through detailed structural analyses, including single-crystal X-ray diffraction, electron microscopy, and density functional theory (DFT), we elucidate the apparent noncrystallographic screw axis and the first example of an atomic scale helical structure bearing a "
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