ArticleRSC advances2024
Optimizing white light emission in Dy(iii) complexes: impact of energy transfer from mono and bidentate ligands on luminescence.
Article in RSC advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Ancillary ligand modulation in fluorinated β-diketonate Dy(iii) complexes: spectroscopic and photophysical investigations.RSC advances · 2026Article
- Tunable Emission in Samarium(III) Complexes for Display Applications: Synthesis, Structural Features and Optoelectronic Investigation.Journal of fluorescence · 2026Article
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Authors and funding
10 authors.
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Abstract
Complexes of dysprosium(iii) ions with 1,1,1,5,5,5-hexafluoro-2,4-pentanedione featuring various mono and bi-dentate neutral ligands have been prepared and thoroughly investigated. The synthesized complexes exhibit an octa-coordinated environment, achieved by stoichiometrically combining organic ligands and Dy(iii) ions. This octa-coordination environment of Dy(iii) ion was confirmed by FT-IR spectroscopy, thermogravimetry and elemental analysis. Near-white light (NWL) is emitted when complexes were exposed to UV radiation, indicating a significant flow of energy from the sensitizing moieties towards the Dy(iii) ion. This NWL emission might have resulted due to a balance between the intensities corresponding to emission peaks at 480 nm (blue) and 575 nm (yellow) in Dy1-Dy3. Emission spectra recorded at different excitation wavelength were utilized to study the tunability of CIE color coordinates. In addition to their high thermal stability, the complexes display bipolar paramagnetic shifts in their NMR spectra. The
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