ArticleAngewandte Chemie (International ed. in English)2024
Interception and Synthetic Application of Diradical and Diene Forms of Dual-Nature Azabicyclic o-Quinodimethanes Generated by 6π-Azaelectrocyclization.
Article in Angewandte Chemie (International ed. in English), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Substituent-Controlled Ring Opening of 1-Substituted Benzocyclobutenes: Electronic Structure and Diradical Character of Ortho-Quinodimethane Intermediates.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Generation of Mono- and BisazabicyclicOrganic letters · 2026Article
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6 authors.
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Abstract
We demonstrate that 2-alkenylarylaldimines and ketimines undergo thermal 6π-azaelectrocyclization to generate a wide range of azabicyclic o-quinodimethanes (o-QDMs). These o-QDMs exist as a hybrid of a diene and a benzylic diradical. The diradical nature was confirmed by their ability to undergo dimerization and react with H-atom donor, 2,2,6,6-tetramethylpiperidin-1-yl)oxyl (TEMPO) and O
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