Evidence map›Paper›PMID 39018429›Full record

ArticleInorganic chemistry2024

Selective Liquid-Liquid Extraction of Thorium(IV) from Rare-Earth Element Mixtures.

Wyatt B Larrinaga, Bailey J Lake, Victoria D Pacanowski, Michael G Patterson, Michael Hudson, Faith M Carlson, Gabriel Heselschwerdt, Steven Balboa, Shannon M Biros, Eric J Werner

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Inorganic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Bioleaching of critical trace metals byFrontiers in microbiology · 2026
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Wyatt B LarrinagaDepartment of Chemistry and Biochemistry, The University of Tampa, 401 West Kennedy Boulevard, Tampa, Florida 33606, United States.ORCID 0009-0009-0416-5121
Bailey J LakeDepartment of Chemistry and Biochemistry, The University of Tampa, 401 West Kennedy Boulevard, Tampa, Florida 33606, United States.
Victoria D PacanowskiDepartment of Chemistry and Biochemistry, The University of Tampa, 401 West Kennedy Boulevard, Tampa, Florida 33606, United States.
Michael G PattersonDepartment of Chemistry and Biochemistry, The University of Tampa, 401 West Kennedy Boulevard, Tampa, Florida 33606, United States.
Michael HudsonDepartment of Chemistry, Grand Valley State University, 1 Campus Drive, Allendale, Michigan 49401, United States.
Faith M CarlsonDepartment of Chemistry, Grand Valley State University, 1 Campus Drive, Allendale, Michigan 49401, United States.
Gabriel HeselschwerdtDepartment of Chemistry, Grand Valley State University, 1 Campus Drive, Allendale, Michigan 49401, United States.
Steven BalboaDepartment of Chemistry, Grand Valley State University, 1 Campus Drive, Allendale, Michigan 49401, United States.
Shannon M BirosDepartment of Chemistry, Grand Valley State University, 1 Campus Drive, Allendale, Michigan 49401, United States.
Eric J WernerDepartment of Chemistry and Biochemistry, The University of Tampa, 401 West Kennedy Boulevard, Tampa, Florida 33606, United States.ORCID 0000-0002-2539-0856

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

One of the major challenges in processing rare-earth element (REE) materials arises from the large amounts of radioactive thorium (Th) that are often found within REE minerals, encouraging enhanced metal separation procedures. We report here a study aimed at developing improved systems for REE processing with the goal of efficient extraction of Th(IV) from acidic solution. A tripodal ligand, TRPN-CMPO-Ph, was prepared that utilizes carbamoylmethylphosphine oxide (CMPO) chelators tethered to a tris(3-aminopropyl)amine (TRPN) capping scaffold. The ligand and its metal complexes were characterized by using elemental analysis, NMR, Fourier transform infrared spectroscopy, mass spectrometry, and luminescence spectroscopy. Using a liquid-liquid metal extraction protocol, TRPN-CMPO-Ph selectively extracts Th(IV) at an efficiency of 79% from a mixture of Th(IV), UO

Identifiers

PMID39018429
PMCPMC11289752

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.