ArticleACS nano2024
Emergence of Band Structure in a Two-Dimensional Metal-Organic Framework upon Hierarchical Self-Assembly.
Article in ACS nano, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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12 citing papers in PubMed.
- Stability and reactivity of Fe-DCA 2D metal-organic frameworks on chemically inert graphene support.RSC advances · 2026Article
- Single cobalt atoms and two oxidation states: on-surface synthesis of a 2D metal-organic frameworkNanoscale · 2026Article
- Zero-Valent Nickel Stabilized in Surface-Supported Metal-Organic Chains.Angewandte Chemie (International ed. in English) · 2026Article
- Metal organic semiconducting structures for electronic band engineering and optoelectronic uses.iScience · 2026Review
- Article
- Spectroscopic Fingerprinting of Coordination-driven Spin States in Metal-organic Architectures.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Spin and Momentum Mapping of Highly Oriented Spinterfaces.Nano letters · 2025Article
- Revealing the Character of Coordination Bonding in 2D Metal-Organic Frameworks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Atomically-defined on-surface synthesis of multilayer metal-organic frameworks.Communications chemistry · 2025Article
- Substrate Stabilized Charge Transfer Scheme In Coverage Controlled 2D Metal Organic Frameworks.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Inverse Design of 2D Altermagnetic Metal-Organic Framework Monolayers from Hückel Theory of Nonbonding Molecular Orbitals.JACS Au · 2025Article
- Band Structure Engineering in 2D Metal-Organic Frameworks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
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Authors and funding
14 authors.
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Abstract
Two-dimensional metal-organic frameworks (2D-MOFs) represent a category of atomically thin materials that combine the structural tunability of molecular systems with the crystalline structure characteristic of solids. The strong bonding between the organic linkers and transition metal centers is expected to result in delocalized electronic states. However, it remains largely unknown how the band structure in 2D-MOFs emerges through the coupling of electronic states in the building blocks. Here, we demonstrate the on-surface synthesis of a 2D-MOF exhibiting prominent π-conjugation. Through a combined experimental and theoretical approach, we provide direct evidence of band structure formation upon hierarchical self-assembly, going from metal-organic complexes to a conjugated two-dimensional framework. Additionally, we identify the robustly dispersive nature of the emerging hybrid states, irrespective of the metallic support type, highlighting the tunability of the band structure through charge transfer from the substrate. Our findings encourage the exploration of band-structure engineering in 2D-MOFs for potential applications in electronics and photonics.
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