Evidence map›Paper›PMID 38987244›Full record

ArticleNature communications2024

Active species in chloroaluminate ionic liquids catalyzing low-temperature polyolefin deconstruction.

Wei Zhang, Rachit Khare, Sungmin Kim, Lillian Hale, Wenda Hu, Chunlin Yuan, Yaoci Sheng, Peiran Zhang, Lennart Wahl, Jiande Mai and 9 more

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Intermolecular Electrophilic Germylation Using GeClAngewandte Chemie (International ed. in English) · 2026
    Article
  3. Article
  4. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

19 authors.

Wei ZhangInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA. wzhangx@outlook.com.ORCID http://orcid.org/0000-0003-4506-6583
Rachit KhareDepartment of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstr. 4, Garching, Germany.
Sungmin KimInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.ORCID http://orcid.org/0000-0001-6602-1320
Lillian HaleInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.
Wenda HuInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.
Chunlin YuanDepartment of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstr. 4, Garching, Germany.
Yaoci ShengDepartment of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstr. 4, Garching, Germany.
Peiran ZhangDepartment of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstr. 4, Garching, Germany.ORCID http://orcid.org/0000-0001-5250-3716
Lennart WahlDepartment of Chemistry and Catalysis Research Center, Technische Universität München, Lichtenbergstr. 4, Garching, Germany.
Jiande MaiInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.
Boda YangInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.
Oliver Y GutiérrezInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.ORCID http://orcid.org/0000-0001-9163-4786
Debmalya RayInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.
John FultonInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.
Donald M CamaioniInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.ORCID http://orcid.org/0000-0002-2213-0960
Jianzhi HuInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.ORCID http://orcid.org/0000-0001-8879-747X
Huamin WangInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.
Mal-Soon LeeInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA.ORCID http://orcid.org/0000-0001-6851-177X
Johannes A LercherInstitute for Integrated Catalysis, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA, USA. johannes.lercher@ch.tum.de.ORCID http://orcid.org/0000-0002-2495-1404

Funding

DOE | SC | Chemical Sciences, Geosciences, and Biosciences Division (Chemical Sciences, Geosciences, and Energy Biosciences) FWP47319DOE | SC | Chemical Sciences, Geosciences, and Biosciences Division (Chemical Sciences, Geosciences, and Energy Biosciences) FWP78459
6 · The paper itself

Abstract

Chloroaluminate ionic liquids selectively transform (waste) polyolefins into gasoline-range alkanes through tandem cracking-alkylation at temperatures below 100 °C. Further improvement of this process necessitates a deep understanding of the nature of the catalytically active species and the correlated performance in the catalyzing critical reactions for the tandem polyolefin deconstruction with isoalkanes at low temperatures. Here, we address this requirement by determining the nuclearity of the chloroaluminate ions and their interactions with reaction intermediates, combining in situ

Identifiers

PMID38987244
PMCPMC11237162

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.