ArticleScience advances2024
Tuning MOF/polymer interfacial pore geometry in mixed matrix membrane for upgrading CO
Article in Science advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
12 citing papers in PubMed.
- Advanced Porous Materials in Mixed Matrix Membranes for COSmall (Weinheim an der Bergstrasse, Germany) · 2026Review
- Stimuli-responsive metal-organic polyhedra-based hydrogel membrane for switchable separations toward COScience advances · 2026Article
- Article
- On-demand linkage cleavage in two-dimensional conjugated metal-organic frameworks for closed-loop recyclable electronics.Science advances · 2026Article
- Embryonic zeolite-mediated suture synthesis of thin and scalable zeolite membranes for tailored gas separation.Nature communications · 2026Article
- Thermal Cyclotrimerization Bridges Polymer-Filler Interfaces for High-Performance COAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Metal-organic framework/graphene nanoribbon/polyimide mixed-matrix membranes for high-temperature HScience advances · 2026Article
- Nitrogen-Doped Borane Cluster Network for High-Performance Supercapacitors Under Universal pH Conditions.ChemSusChem · 2026Article
- MOF surface morphology governs interfacial pore architecture and COChemical science · 2025Review
- Harnessing Pore Size in COF Membranes: A Concentration Gradient-Driven Molecular Dynamics Study on Enhanced HACS applied materials & interfaces · 2025Article
- Simultaneously Enhanced Permeability and Selectivity of Pebax-1074-Based Mixed-Matrix Membrane for COMembranes · 2025Article
- A review of metal-organic frameworks and polymers in mixed matrix membranes for COBeilstein journal of nanotechnology · 2025Review
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The current paradigm considers the control of the MOF/polymer interface mostly for achieving a good compatibility between the two components to ensure the fabrication of continuous mixed-matrix metal-organic framework (MMMOF) membranes. Here, we unravel that the interfacial pore shape nanostructure plays a key role for an optimum molecular transport. The prototypical ultrasmall pore AlFFIVE-1-Ni MOF was assembled with the polymer PIM-1 to design a composite with gradually expanding pore from the MOF entrance to the MOF/polymer interfacial region. Concentration gradient-driven molecular dynamics simulations demonstrated that this pore nanostructuring enables an optimum guided path for the gas molecules at the MOF/polymer interface that decisively leads to an acceleration of the molecular transport all along the MMMOF membrane. This numerical prediction resulted in the successful fabrication of a [001]-oriented nanosheets AlFFIVE-1-Ni/PIM-1 MMMOF membrane exhibiting an excellent CO
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.