ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024
Unexpected Molecular Sieving of Xylene Isomer Using Tethered Ligand in Polymer-Metal-Organic Frameworks (polyMOFs).
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
4 citing papers in PubMed.
- Production of aromatics from high density polyethylene over a hierarchical zeolite synthesised from steam-assisted crystallisation.Nature communications · 2026Article
- Highly Selective Adsorption of Para-Xylene, Ethylbenzene, and Explicit Exclusion of Ortho-Xylene from Xylene Isomers Using a Pillar-Layered MOF with Tuned Pore Channels.Angewandte Chemie (International ed. in English) · 2025Article
- Molecular Mechanism Behind the Capture of Fluorinated Gases by Metal-Organic Frameworks.Nano-micro letters · 2025Review
- Unexpected Molecular Sieving of Xylene Isomer Using Tethered Ligand in Polymer-Metal-Organic Frameworks (polyMOFs).Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Promising advances in adsorption technology can lead to energy-efficient solutions in industrial sectors. This work presents precise molecular sieving of xylene isomers in the polymer-metal-oragnic framework (polyMOF), a hybrid porous material derived from the parent isoreticular MOF-1 (IRMOF-1). PolyMOFs are synthesized by polymeric ligands bridged by evenly spaced alkyl chains, showing reduced pore sizes and enhanced stabilities compared to its parent material due to tethered polymer bridge within the pores while maintaining the original rigid crystal lattice. However, the exact configuration of the ligands within the crystals remain unclear, posing hurdles to predicting the adsorption performances of the polyMOFs. This work reveals that the unique pore structure of polyIRMOF-1-7a can discriminate xylene isomers with sub-angstrom size differences, leading to highly selective adsorption of p-xylene over other isomers and alkylbenzenes in complex liquid mixtures (α
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Registered trials
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