ArticleScience advances2024
The role of the plasmon in interfacial charge transfer.
Article in Science advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
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The trial behind it
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Who cites it
20 citing papers in PubMed.
- Plasmonic metasurface microfluidic accelerates redox reactions for rapid phenotypic antibiotic susceptibility testing.Science advances · 2026Article
- Energy-Resolved Femtosecond Dynamics of Plasmon-Induced Hole Injection at Au/GaN Heterointerfaces.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Single-particle catalytic monitoring of interfacial charge dynamics during light-driven CdS shell growth on Au nanocubes.Nature communications · 2026Article
- Quasi-BIC metasurfaces enable rapid, localized singlet-oxygen generation.Light, science & applications · 2026Article
- Conundrums of Localized Surface Plasmon Resonance Biosensors.Small (Weinheim an der Bergstrasse, Germany) · 2026Review
- Trace Alloying Unleashed: AuPt Nanoalloys Strategy Preserves Plasmonic Properties on Au Nanobipyramids While Boosting Electron Transfer for Visible Light Ammonia Synthesis.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Core-Shell Plasmonic Nanocomposites with Synergistic Photothermal and Photochemical Activity for Biomedical Applications.Nanomaterials (Basel, Switzerland) · 2026Review
- Picosecond Stabilization of Transferred Charge Carriers at Plasmonic Metal-Molecule Interfaces.Angewandte Chemie (International ed. in English) · 2026Article
- Optical and electrical probing of plasmonic metal-molecule interactions.Science advances · 2025Article
- Charge transfer at the plasmon-molecule interfaces controls the collective chiroptical responses.Nature communications · 2025Article
- Ultrafast nonthermal electron transfer at plasmonic interfaces.Nature communications · 2025Article
- Plasmonic pathway to hybrid nanomaterials through energy transfer.Science advances · 2025Article
- Review
- Harmonic-induced plasmonic resonant energy transfer between metal and semiconductor nanoparticles.Science advances · 2025Article
- Plasmonic catalysis with bi-resonant noble metal-CuFeSNanotechnology · 2025Article
- Plasmonic Hot-Carrier Engineering at Bimetallic Nanoparticle/Semiconductor Interfaces: A Computational Perspective.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Efficient Size-Dependent Hot Electron Transfer from Au to TiONano letters · 2025Article
- Fine-tuning d-p hybridization in Ni-BNature communications · 2025Article
- Article
- Controlling Plasmonic Catalysis via Strong Coupling with Electromagnetic Resonators.Nano letters · 2024Article
Corrections and comments
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Authors and funding
15 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The lack of a detailed mechanistic understanding for plasmon-mediated charge transfer at metal-semiconductor interfaces severely limits the design of efficient photovoltaic and photocatalytic devices. A major remaining question is the relative contribution from indirect transfer of hot electrons generated by plasmon decay in the metal to the semiconductor compared to direct metal-to-semiconductor interfacial charge transfer. Here, we demonstrate an overall electron transfer efficiency of 44 ± 3% from gold nanorods to titanium oxide shells when excited on resonance. We prove that half of it originates from direct interfacial charge transfer mediated specifically by exciting the plasmon. We are able to distinguish between direct and indirect pathways through multimodal frequency-resolved approach measuring the homogeneous plasmon linewidth by single-particle scattering spectroscopy and time-resolved transient absorption spectroscopy with variable pump wavelengths. Our results signify that the direct plasmon-induced charge transfer pathway is a promising way to improve hot carrier extraction efficiency by circumventing metal intrinsic decay that results mainly in nonspecific heating.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.