ArticleProceedings of the National Academy of Sciences of the United States of America2024
Stabilizing Ti
Article in Proceedings of the National Academy of Sciences of the United States of America, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 20 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
20 citing papers in PubMed.
- Pure oxygen terminated MXenes prepared by NaOH/NaI eutectic molten salt.Fundamental research · 2026Article
- Ultrafast energy transfer across Pd/MXene interface via hot phonon-electron interactions.Science advances · 2026Article
- Tuning Anisotropic Optical Properties of Inorganic and Hybrid Organic-Inorganic MXenes via Topochemical Surface Modification.Nano letters · 2026Article
- Recent Advances in Two-Dimensional Metallic MXenes as High-Performance Saturable Absorbers.Nanomaterials (Basel, Switzerland) · 2026Review
- Double-Transition-Metal MXenes: Multimetallic 2D Platforms for Next-Generation Biomedicine.Advanced materials (Deerfield Beach, Fla.) · 2026Review
- From 2D MXenes to 3D Carbides: Transformation of TiNano letters · 2026Article
- Water-Induced Local Redox Reactions on Individual TiAngewandte Chemie (International ed. in English) · 2026Article
- Lignin-Containing Nanocellulose Mediated Interlayer Modulation Unlocks Stable and Redispersible MXene.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- A Machine Learning Framework for Modeling Ensemble Properties of Atomically Disordered Materials.ACS nano · 2025Article
- Tribology of MXene Materials: Advances, Challenges, and Future Directions.Materials (Basel, Switzerland) · 2025Review
- Article
- Selective Wet Etching for Scalable Nanofabrication of Patterned MXene Thin Films.Nano letters · 2025Article
- Covalent Surface Modification of Hydrophobic Alkoxides on TiAdvanced materials (Deerfield Beach, Fla.) · 2025Article
- Future development directions of high-temperature strain gauges: a comprehensive review of structure and performance characteristics.Nanoscale advances · 2025Review
- Article
- TiAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Longevous Protic Hybrid Supercapacitors Using Bimetallic Prussian Blue Analogue/rGO-Based Nanocomposite Against MXene Anode.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- 3D porous structure of ionic liquid-delaminated TiScientific reports · 2025Article
- TiThe journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Stabilizing TiProceedings of the National Academy of Sciences of the United States of America · 2024Article
Corrections and comments
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Authors and funding
12 authors.
Funding
Abstract
MXenes have demonstrated potential for various applications owing to their tunable surface chemistry and metallic conductivity. However, high temperatures can accelerate MXene film oxidation in air. Understanding the mechanisms of MXene oxidation at elevated temperatures, which is still limited, is critical in improving their thermal stability for high-temperature applications. Here, we demonstrate that Ti[Formula: see text]C[Formula: see text]T[Formula: see text] MXene monoflakes have exceptional thermal stability at temperatures up to 600[Formula: see text]C in air, while multiflakes readily oxidize in air at 300[Formula: see text]C. Density functional theory calculations indicate that confined water between Ti[Formula: see text]C[Formula: see text]T[Formula: see text] flakes has higher removal energy than surface water and can thus persist to higher temperatures, leading to oxidation. We demonstrate that the amount of confined water correlates with the degree of oxidation in stacked flakes. Confined water can be fully removed by vacuum annealing Ti[Formula: see text]C[Formula: see text]T[Formula: see text] films at 600[Formula: see text]C, resulting in substantial stability improvement in multiflake films (can withstand 600[Formula: see text]C in air). These findings provide fundamental insights into the kinetics of confined water and its role in Ti[Formula: see text]C[Formula: see text]T[Formula: see text] oxidation. This work enables the use of stable monoflake MXenes in high-temperature applications and provides guidelines for proper vacuum annealing of multiflake films to enhance their stability.
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Registered trials
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