ArticleACS applied optical materials2024
Highly Luminescent TCNQ in Melamine.
Article in ACS applied optical materials, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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5 authors.
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Abstract
Optical properties of molecules change drastically as a result of interactions with surrounding environments as observed in solutions, clusters, and aggregates. Here, we make 7,7,8,8-tetracyanoquinodimethane (TCNQ) highly luminescent by encapsulating it in crystalline melamine. Colored single crystals are synthesized by slow evaporation of aqueous tetrahydrofuran solutions of melamine and TCNQ. Single-crystal X-ray diffraction reveals the lattice structure of pure melamine, meaning that the color is of impurities. Both mass spectrometry and UV-vis spectroscopy combined with density-functional theory calculations elucidate that the impurity species are neutral TCNQ and its oxidation product, dicyano-
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