ArticleCell reports. Physical science2024
Randomizing the growth of silica nanofibers for whiteness.
Article in Cell reports. Physical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Two-Factor Authentication Inspired Optical Security of Information Enabled by Silica Nanofibers.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Heterologous biosynthesis of cotylenol and concise synthesis of fusicoccane diterpenoids.Beilstein journal of organic chemistry · 2025Article
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Authors and funding
6 authors.
Funding
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Abstract
In colloids, the shape influences the function. In silica, straight nanorods have already been synthesized from water-in-oil emulsions. By contrast, curly silica nanofibers have been less reported because the underlying growth mechanism remains unexplored, hindering further morphology control for applications. Herein, we describe the synthetic protocol for silica nanofibers with a tunable curliness based on the control of the water-in-oil emulsion droplets. Systematically decreasing the droplet size and increasing their contact angle, the Brownian motion of the droplets intensifies during the silica growth, thus increasing the random curliness of the nanofibers. This finding is supported by simplistic theoretical arguments and experimentally verified by varying the temperature to finely tune the curliness. Assembling these nanofibers toward porous disordered films enhances multiple scattering in the visible range, resulting in increased whiteness in contrast to films constructed by spherical and rod-like building units, which can be useful for, e.g., coatings and pigments.
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