ArticleProceedings of the National Academy of Sciences of the United States of America2024
The codriven assembly of molecular metalla-links ([Formula: see text], [Formula: see text]) and metalla-knots ([Formula: see text], [Formula: see text]) via coordination and noncovalent interactions.
Article in Proceedings of the National Academy of Sciences of the United States of America, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Assembly delivery of bioactive matters: Advances, challenges, and prospects.Journal of advanced research · 2026Review
- Efficient synthesis of complex supramolecular topologies via coordination angle modulation.National science review · 2026Article
- Precise synthesis of π-conjugated [3]catenanes and Solomon link for photothermal responses via a dual-tuning strategy.Nature communications · 2026Article
- Discrete Heterotrimetallic Assemblies Based on Rod-Shaped FeChemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Formation of a PdJACS Au · 2025Article
- Stereoselective construction of coconformational mechanically helical and topologically chiral [2]catenanes induced by point chirality.Proceedings of the National Academy of Sciences of the United States of America · 2025Article
- The Interplay Between Component Denticity and Flexibility Promotes the Formation of [AgAngewandte Chemie (International ed. in English) · 2025Article
- Functional Post-Synthetic Chemistry of Metal-Organic Cages According to Molecular Architecture and Specific Geometry of Origin.Molecules (Basel, Switzerland) · 2025Review
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Authors and funding
4 authors.
Funding
Abstract
Although mechanically interlocked molecules (MIMs) display unique properties and functions associated with their intricate connectivity, limited assembly strategies are available for their synthesis. Herein, we presented a synergistic assembly strategy based on coordination and noncovalent interactions (π-π stacking and CH⋯π interactions) to selectively synthesize molecular closed three-link chains ([Formula: see text] links), highly entangled figure-eight knots ([Formula: see text] knots), trefoil knot ([Formula: see text] knot), and Borromean ring ([Formula: see text] link). [Formula: see text] links can be created by the strategic assembly of nonlinear multicurved ligands incorporating a furan or phenyl group with the long binuclear half-sandwich organometallic Cp*Rh
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