ArticleChemical science2024
Photolysis-driven bond activation by thorium and uranium tetraosmate polyhydride complexes.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron-Iridium Clusters.Organometallics · 2025Article
- COChemical communications (Cambridge, England) · 2024Article
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Authors and funding
7 authors.
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Abstract
Transition metal multimetallic complexes have seen intense study due to their unique bonding and potential for cooperative reactivity, but actinide-transition metal (An-TM) species are far less understood. We have synthesized uranium- and thorium-osmium heterometallic polyhydride complexes in order to study An-Os bonding and investigate the reactivity of An-Os interactions. Computational studies suggest the presence of a significant bonding interaction between the actinide center and the four coordinated osmium centers supported by bridging hydrides. Upon photolysis, these complexes undergo intramolecular C-H activation with the formation of an Os-Os bond, while the thorium complex may activate an additional C-H bond of the benzene solvent, resulting in a μ-η
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