ArticleJACS Au2024
Bromide-Mediated Silane Oxidation: A Practical Counter-Electrode Process for Nonaqueous Deep Reductive Electrosynthesis.
Article in JACS Au, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Deep reduction in electrosynthesis.Nature chemistry · 2026Review
- C(spACS electrochemistry · 2026Article
- Selective Electrochemical Defluorinative Hydroxymethylation toward Difluoro-Substituted Alcohol Building Blocks.Organic letters · 2026Article
- Electrochemical Synthesis of Isolated Fluoride Reagents from PFAS.Journal of the American Chemical Society · 2026Article
- Electrochemical Deoxygenative Silylation of Alcohols.Angewandte Chemie (International ed. in English) · 2025Article
- Bromo-Substituted Phenylbenzothiazole Cyclometalating Ligands for the Development of Reverse Saturable Absorption Materials.Inorganic chemistry · 2025Article
- Borohydride Oxidation as Counter Reaction in Reductive Electrosynthesis.Angewandte Chemie (International ed. in English) · 2025Article
- Synthesis of SrAlDiscover nano · 2025Article
- The Future of Electro-organic Synthesis in Drug Discovery and Early Development.ACS organic & inorganic Au · 2024Review
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Authors and funding
6 authors.
Funding
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Abstract
The counter-electrode process of an organic electrochemical reaction is integral for the success and sustainability of the process. Unlike for oxidation reactions, counter-electrode processes for reduction reactions remain limited, especially for deep reductions that apply very negative potentials. Herein, we report the development of a bromide-mediated silane oxidation counter-electrode process for nonaqueous electrochemical reduction reactions in undivided cells. The system is found to be suitable for replacing either sacrificial anodes or a divided cell in several reported reactions. The conditions are metal-free, use inexpensive reagents and a graphite anode, are scalable, and the byproducts are reductively stable and readily removed. We showcase the translation of a previously reported divided cell reaction to a >100 g scale in continuous flow.
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Registered trials
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