ArticleNature chemistry2024
Hydrogen splitting at a single phosphorus centre and its use for hydrogenation.
Article in Nature chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- T-Shaped Stibenium(III) Cation: Hydrostibination Without Sb─H Bond.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth-Ligand Cooperation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Bis(pyridino-Inorganic chemistry · 2026Article
- Bridging Lewis acidic antimony centers with electron-withdrawing carborane cages.Chemical science · 2026Article
- Article
- Structurally Constrained Stibenium: Metallomimetic C-Si Bond Activation.Angewandte Chemie (International ed. in English) · 2026Article
- Isolation and Reactivity of a Square-Planar Trisamido Silane.Angewandte Chemie (International ed. in English) · 2026Article
- Photochemical activation of pincer-ligated phosphoranides: mechanistic insight for reduction of aryl halides.Chemical science · 2026Article
- Secondary Phosphines Bearing N-Heterocyclic Imine Groups: Polarity Umpolung of Highly Electron-Rich P-H Bonds.Inorganic chemistry · 2025Article
- Synthesis of PChemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Strain-Release Driven Arsenium Ion Bond Insertion.Angewandte Chemie (International ed. in English) · 2025Article
- Direct OJACS Au · 2025Article
- Hexaphenyl-1,2-Diphosphonium Dication [PhJournal of the American Chemical Society · 2025Article
- A focus on phosphinophosphination of apolar bonds by a structurally constrained P-P bonded system.Chemical science · 2025Article
- Structural constraint at a P-P bond: phosphinophosphination of alkenes, alkynes, and carbonyls by a concerted mechanism.Chemical science · 2025Article
- Phosphorus-mediated hydrogenation catalysis.Nature chemistry · 2024Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Catalytic processes are largely dominated by transition-metal complexes. Main-group compounds that can mimic the behaviour of the transition-metal complexes are of great interest due to their potential to substitute or complement transition metals in catalysis. While a few main-group molecular centres were shown to activate dihydrogen via the oxidative addition process, catalytic hydrogenation using these species has remained challenging. Here we report the synthesis, isolation and full characterization of the geometrically constrained phosphenium cation with the 2,6-bis(o-carborano)pyridine pincer-type ligand. Notably, this cation can activate the H-H bond by oxidative addition to a single P
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Registered trials
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