ArticleJournal of the American Chemical Society2024
Mechanochemical Fabrication of Full-Color Luminescent Materials from Aggregation-Induced Emission Prefluorophores for Information Storage and Encryption.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Time-Encoded Geometric Encryption Enabled by Shape-Memory Hydrogel with Photoisomerization-Gated Autonomous Recovery.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Small Organic Molecule-Based Multicolor Fluorescent Smart Materials: From Design Principles and Optical Properties to Versatile Applications.ACS central science · 2026Review
- Programmable wavelength- and time-dependent multicolor afterglow in polyvinyl alcoholChemical science · 2026Article
- Aggregation-induced emission luminogen in ternary organic bulk-heterojunction for efficient perovskite-organic tandem solar cells.Nature communications · 2026Article
- Photoresponsive DNA steganography for secure information transmission by nanopore.National science review · 2026Article
- Fluorescence mechanism of poly(2-vinylnaphthalene) driven by local ordering and restricted motion.RSC advances · 2026Article
- Room-temperature photoluminescence in monocarboxylate-protected silver nanoclusters via steric hindrance-induced interfacial structure locking.Nature communications · 2025Article
- Synthesis and Characterization of Multilayer 3D Chiral Polymers with Enhanced Optical Properties.Molecules (Basel, Switzerland) · 2025Article
- Multi-mode geometrically gated encryption with 4D morphing hydrogel.Nature communications · 2025Article
- Mechanoluminescence from Organic-Inorganic Metal Halide Perovskite Derivative.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The development of luminescent materials via mechanochemistry embodies a compelling yet intricate frontier within materials science. Herein, we delineate a methodology for the synthesis of brightly luminescent polymers, achieved by the mechanochemical coupling of aggregation-induced emission (AIE) prefluorophores with generic polymers. An array of AIE moieties tethered to the 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) radical are synthesized as prefluorophores, which initially exhibit weak fluorescence due to intramolecular quenching. Remarkably, the mechanical coupling of these prefluorophores with macromolecular radicals, engendered through ball milling of generic polymers, leads to substantial augmentation of fluorescence within the resultant polymers. We meticulously evaluate the tunable emission of the AIE-modified polymers, encompassing an extensive spectrum from the visible to the near-infrared region. This study elucidates the potential of such materials in stimuli-responsive systems with a focus on information storage and encryption displays. By circumventing the complexity inherent to the conventional synthesis of luminescent polymers, this approach contributes a paradigm to the field of AIE-based polymers with implications for advanced technological applications.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.