Symmetry breaking of highly symmetrical nanoclusters for triggering highly optical activity.

Xiao Wei, Hao Li, Honglei Shen, Chuanjun Zhou, Shuxin Wang, Xi Kang, Manzhou Zhu

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Article in Fundamental research, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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7 authors.

Xiao WeiDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials. Anhui University, Hefei 230601, China.

Hao LiDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials. Anhui University, Hefei 230601, China.

Honglei ShenDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials. Anhui University, Hefei 230601, China.

Chuanjun ZhouDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials. Anhui University, Hefei 230601, China.

Shuxin WangDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials. Anhui University, Hefei 230601, China.

Xi KangDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials. Anhui University, Hefei 230601, China.

Manzhou ZhuDepartment of Chemistry and Centre for Atomic Engineering of Advanced Materials, Key Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of Education, Institutes of Physical Science and Information Technology and Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials. Anhui University, Hefei 230601, China.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Developing new approaches to fulfill the enantioseparation of nanocluster racemates and construct cluster-based nanomaterials with optical activity remains highly desired in cluster science, because it is an essential prerequisite for fundamental research and extensive applications of these nanomaterials. We herein propose a strategy termed "active-site exposing and partly re-protecting" to trigger the symmetry breaking of highly symmetrical nanoclusters and to render cluster crystals optically active. The vertex PPh

Indexed as

Atomically precise nanoclusterCircularly polarized luminescentEnantioseparationPhotoluminescenceSymmetry breaking

Identifiers

PMID38933845

DOI10.1016/j.fmre.2022.03.007

PMCPMC11197546

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