Evidence map›Paper›PMID 38932003›Full record

ReviewPolymers2024

Synergistic Construction of Sub-Nanometer Channel Membranes through MOF-Polymer Composites: Strategies and Nanofiltration Applications.

Qian Chen, Ying Tang, Yang-Min Ding, Hong-Ya Jiang, Zi-Bo Zhang, Wei-Xing Li, Mei-Ling Liu, Shi-Peng Sun

Abstract readReview
In one paragraph

Review in Polymers, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Review
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Qian ChenState Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membranes, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.
Ying TangState Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membranes, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.
Yang-Min DingState Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membranes, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.
Hong-Ya JiangState Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membranes, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.
Zi-Bo ZhangState Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membranes, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.
Wei-Xing LiState Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membranes, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.ORCID 0000-0003-0247-7083
Mei-Ling LiuState Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membranes, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.ORCID 0000-0001-7943-3658
Shi-Peng SunState Key Laboratory of Materials-Oriented Chemical Engineering, National Engineering Research Center for Special Separation Membranes, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.

Funding

China Postdoctoral Science Foundation 2023M741664Jiangsu Future Membrane Technology Innovation Center BM2021804National Natural Science Foundation of China 22208150Postgraduate Research & Practice Innovation Program of Jiangsu Province KYCX23_1394
6 · The paper itself

Abstract

The selective separation of small molecules at the sub-nanometer scale has broad application prospects in the field, such as energy, catalysis, and separation. Conventional polymeric membrane materials (e.g., nanofiltration membranes) for sub-nanometer scale separations face challenges, such as inhomogeneous channel sizes and unstable pore structures. Combining polymers with metal-organic frameworks (MOFs), which possess uniform and intrinsic pore structures, may overcome this limitation. This combination has resulted in three distinct types of membranes: MOF polycrystalline membranes, mixed-matrix membranes (MMMs), and thin-film nanocomposite (TFN) membranes. However, their effectiveness is hindered by the limited regulation of the surface properties and growth of MOFs and their poor interfacial compatibility. The main issues in preparing MOF polycrystalline membranes are the uncontrollable growth of MOFs and the poor adhesion between MOFs and the substrate. Here, polymers could serve as a simple and precise tool for regulating the growth and surface functionalities of MOFs while enhancing their adhesion to the substrate. For MOF mixed-matrix membranes, the primary challenge is the poor interfacial compatibility between polymers and MOFs. Strategies for the mutual modification of MOFs and polymers to enhance their interfacial compatibility are introduced. For TFN membranes, the challenges include the difficulty in controlling the growth of the polymer selective layer and the performance limitations caused by the "trade-off" effect. MOFs can modulate the formation process of the polymer selective layer and establish transport channels within the polymer matrix to overcome the "trade-off" effect limitations. This review focuses on the mechanisms of synergistic construction of polymer-MOF membranes and their structure-nanofiltration performance relationships, which have not been sufficiently addressed in the past.

Indexed as

functionalMOFmolecular separationnanofiltration membranespolymer

Identifiers

PMID38932003
PMCPMC11207757

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.