Evidence map›Paper›PMID 38928034›Full record

ArticleInternational journal of molecular sciences2024

Superelectrophilic Activation of Phosphacoumarins towards Weak Nucleophiles via Brønsted Acid Assisted Brønsted Acid Catalysis.

Alena V Zalaltdinova, Yulia M Sadykova, Almir S Gazizov, Atabek K Smailov, Victor V Syakaev, Daria P Gerasimova, Elena A Chugunova, Nurgali I Akylbekov, Rakhmetulla U Zhapparbergenov, Nurbol O Appazov and 4 more

Abstract read
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In one paragraph

Article in International journal of molecular sciences, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors.

Alena V ZalaltdinovaFRC Kazan Scientific Center, Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Science, Arbuzova Str., 8, 420088 Kazan, Russia.ORCID 0000-0002-4822-7330
Yulia M SadykovaFRC Kazan Scientific Center, Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Science, Arbuzova Str., 8, 420088 Kazan, Russia.
Almir S GazizovFRC Kazan Scientific Center, Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Science, Arbuzova Str., 8, 420088 Kazan, Russia.ORCID 0000-0001-9899-9606
Atabek K SmailovKazan National Research Technological University, Karl Marx Str., 68, 420015 Kazan, Russia.
Victor V SyakaevFRC Kazan Scientific Center, Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Science, Arbuzova Str., 8, 420088 Kazan, Russia.
Daria P GerasimovaFRC Kazan Scientific Center, Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Science, Arbuzova Str., 8, 420088 Kazan, Russia.ORCID 0000-0001-9770-196X
Elena A ChugunovaFRC Kazan Scientific Center, Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Science, Arbuzova Str., 8, 420088 Kazan, Russia.ORCID 0000-0002-9371-1877
Nurgali I AkylbekovLaboratory of Engineering Profile "Physical and Chemical Methods of Analysis", Korkyt Ata Kyzylorda University, Aitekebie Str., 29A, Kyzylorda 120014, Kazakhstan.ORCID 0000-0002-7584-9741
Rakhmetulla U ZhapparbergenovLaboratory of Engineering Profile "Physical and Chemical Methods of Analysis", Korkyt Ata Kyzylorda University, Aitekebie Str., 29A, Kyzylorda 120014, Kazakhstan.
Nurbol O AppazovLaboratory of Engineering Profile "Physical and Chemical Methods of Analysis", Korkyt Ata Kyzylorda University, Aitekebie Str., 29A, Kyzylorda 120014, Kazakhstan.ORCID 0000-0001-8765-3386
Alexander R BurilovFRC Kazan Scientific Center, Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Science, Arbuzova Str., 8, 420088 Kazan, Russia.
Michail A PudovikFRC Kazan Scientific Center, Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Science, Arbuzova Str., 8, 420088 Kazan, Russia.
Igor V AlabuginDepartment of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306, USA.ORCID 0000-0001-9289-3819
Oleg G SinyashinFRC Kazan Scientific Center, Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Science, Arbuzova Str., 8, 420088 Kazan, Russia.

Funding

Russian Science Foundation and the Cabinet of Ministers of the Republic of Tatarstan 23-23-10020Science Committee of the Ministry of Science and Higher Education of the Republic of Kazakhstan AP19677249
6 · The paper itself

Abstract

The electrophilic activation of various substrates via double or even triple protonation in superacidic media enables reactions with extremely weak nucleophiles. Despite the significant progress in this area, the utility of organophosphorus compounds as superelectrophiles still remains limited. Additionally, the most common superacids require a special care due to their high toxicity, exceptional corrosiveness and moisture sensitivity. Herein, we report the first successful application of the "Brønsted acid assisted Brønsted acid" concept for the superelectrophilic activation of 2-hydroxybenzo[

Indexed as

Organophosphorus CompoundsAcidsCatalysisHydrogen BondingMolecular StructureAcidsOrganophosphorus Compoundsacid catalysisareneselectrophilicityphosphacoumarins

Identifiers

PMID38928034
PMCPMC11203683

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.