ArticleJournal of the American Chemical Society2024
Enzyme-like Acyl Transfer Catalysis in a Bifunctional Organic Cage.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Towards next generation enzyme mimics through local electric field control in organic cage catalysts.Chemical science · 2026Article
- Confined Cationic Covalent Organic Cages Enable Oxidant-Free Hofmann-Löffler-Freytag/Cyclization Sequences.Angewandte Chemie (International ed. in English) · 2026Article
- Bifunctional Catalysis of a Crossed Aldol Condensation by Diamines: Impact of Tether Composition and Length.The Journal of organic chemistry · 2026Article
- Selective photocatalytic oxidative cleavage of terminal alkynes to carboxylic acids within a water-soluble PdChemical science · 2026Article
- Chiral inheritance effect in the reactive cystine-based coassembly system.Nature communications · 2026Article
- Enabling technology for accelerated discovery of supramolecular materials.Chemical science · 2025Review
- A Synthetic Lectin for Glucuronate.ACS central science · 2025Article
- Bifunctional Catalysis of Aldol Reactions by Foldamer Dihydrazides: Assessment of Conformational Preorganization.Journal of the American Chemical Society · 2025Article
- Fluoride Enhances Alcohol Binding Within a Trigonal-Prismatic Metal-Organic Capsule.Angewandte Chemie (International ed. in English) · 2025Article
- Computational Study of Alkyne-Acid Cycloisomerization in Gold-Functionalized Resorcinarene Cavitand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Dissecting the Effects of Cage Structure in the Catalytic Activation of Imide Chlorenium-Ion Donors.Journal of the American Chemical Society · 2025Article
- Dual Activation Modes Enable Bifunctional Catalysis of Aldol Reactions by Flexible Dihydrazides.Journal of the American Chemical Society · 2025Article
- Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages.Beilstein journal of organic chemistry · 2025Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Amide-based organic cage cavities are, in principle, ideal enzyme active site mimics. Yet, cage-promoted organocatalysis has remained elusive, in large part due to synthetic accessibility of robust and functional scaffolds. Herein, we report the acyl transfer catalysis properties of robust, hexaamide cages in organic solvent. Cage structural variation reveals that esterification catalysis with an acyl anhydride acyl carrier occurs only in bifunctional cages featuring internal pyridine motifs and two crucial antipodal carboxylic acid groups.
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Registered trials
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