ArticleNature communications2024
Nanoconfinement steers nonradical pathway transition in single atom fenton-like catalysis for improving oxidant utilization.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 33 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
33 citing papers in PubMed.
- Interlayer Confinement Steers Peracetic Acid Activation Toward Nearly Exclusive Singlet Oxygen Generation.Angewandte Chemie (International ed. in English) · 2026Article
- Vertical Through‑Bond Co─O─Mo Bridge Enables Dual‑Site Nonradical Selective Oxidation.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Molecular oxygen confinement ladder enables stable electro-Fenton treatment of nanofiltration concentrate.Environmental science and ecotechnology · 2026Article
- Bioinspired Porphyrin-Based Catalysts From Temporospatial Confined Frameworks for Ultrafast Removal of Sulfaclozine.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Low-gas-flow strategy boosts hierarchical porosity of ZIF-8 single-atom catalysts for efficient adsorption-driven degradation.Nature communications · 2026Article
- Engineering N-site isomerism in donor-acceptor covalent organic frameworks for efficient Fenton-like water purification.Nature communications · 2026Article
- Bioinspired architected catalyst for efficient water purification: Bridging reactivity, reusability, and catalytic component utilization.Science advances · 2026Article
- Programmable Control Over Radical and Non‑Radical Pathways in Fenton‑Like Catalysis via Carbon‑Encapsulated Iron Nanoreactors.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- Strain-Engineered FeNSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Asymmetric Single-Atom Catalysts Govern Diffusible and Non-Diffusible Non-Radical Pathways for Selective Degradation of Antibiotic Resistance Genes.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Superexchange-Assisted Fe(IV)=O Chain Formation on Scalable Iron Single-Atom Catalysts for Low-Chemical Water Purification in Flow.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Cobalt Single-Atom Catalysts for Ultrafast Sulfamethoxazole Degradation: Unveiling the Chloride-Ion-Enhanced Formation of Co(IV)=O.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Breaking the activity-selectivity trade-off in Fenton-like catalysis by d-orbital modulation of single-atom sites within a nano-island-like structure.Nature communications · 2026Article
- Reactive Polymeric Membranes for Advanced Water Treatment: Bridging Mechanisms, Kinetics and Scalable Deployment.Polymers · 2026Review
- Long-range electronic interactions of tubular single-atom Cu-NNature communications · 2026Article
- Built-in electric field activates endogenous redox couple for self-sustained Fenton-like reaction.Nature communications · 2026Article
- Ligand-Wise Stripping Dictates Metal Ensemble Catalysts for Selective Oxidation of Biomass-Derived 5-Hydroxymethylfurfural.Nano-micro letters · 2026Article
- Sabatier-Adjusted d-Band Centers of Scalable Asymmetric Iron Sites toward Dynamic Nonradical Network for Fast Mineralization with Low-Amount Oxidant.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Nanoconfinement-Steered Molecular Preorganization Enables Efficient Monoethanolamine Degradation through Electronically Modulated High-Valent Iron-Oxo Pathways.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Nanoconfined Cu─O─Mo Asymmetric Sites Enable Ambient Spontaneous OAdvanced materials (Deerfield Beach, Fla.) · 2026Article
Corrections and comments
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Authors and funding
11 authors.
Funding
Abstract
The introduction of single-atom catalysts (SACs) into Fenton-like oxidation promises ultrafast water pollutant elimination, but the limited access to pollutants and oxidant by surface catalytic sites and the intensive oxidant consumption still severely restrict the decontamination performance. While nanoconfinement of SACs allows drastically enhanced decontamination reaction kinetics, the detailed regulatory mechanisms remain elusive. Here, we unveil that, apart from local enrichment of reactants, the catalytic pathway shift is also an important cause for the reactivity enhancement of nanoconfined SACs. The surface electronic structure of cobalt site is altered by confining it within the nanopores of mesostructured silica particles, which triggers a fundamental transition from singlet oxygen to electron transfer pathway for 4-chlorophenol oxidation. The changed pathway and accelerated interfacial mass transfer render the nanoconfined system up to 34.7-fold higher pollutant degradation rate and drastically raised peroxymonosulfate utilization efficiency (from 61.8% to 96.6%) relative to the unconfined control. It also demonstrates superior reactivity for the degradation of other electron-rich phenolic compounds, good environment robustness, and high stability for treating real lake water. Our findings deepen the knowledge of nanoconfined catalysis and may inspire innovations in low-carbon water purification technologies and other heterogeneous catalytic applications.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.