Evidence map›Paper›PMID 38903226›Full record

ArticleChemical science2024

Stabilization of Ni-containing Keggin-type polyoxometalates with variable oxidation states as novel catalysts for electrochemical water oxidation.

Xiang Li, Bryan Kit Yue Ng, Ping-Luen Ho, Chunbo Jia, Jining Shang, Tatchamapan Yoskamtorn, Xuelei Pan, Yiyang Li, Guangchao Li, Tai-Sing Wu and 4 more

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Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors.

Xiang LiDepartment of Chemistry, University of Oxford Oxford OX1 3QR UK edman.tsang@chem.ox.ac.uk.ORCID https://orcid.org/0000-0002-3782-2636
Bryan Kit Yue NgDepartment of Chemistry, University of Oxford Oxford OX1 3QR UK edman.tsang@chem.ox.ac.uk.ORCID https://orcid.org/0000-0003-1940-178X
Ping-Luen HoDepartment of Chemistry, University of Oxford Oxford OX1 3QR UK edman.tsang@chem.ox.ac.uk.ORCID https://orcid.org/0000-0002-3911-7973
Chunbo JiaDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University Shanghai 200438 China heyonghe@fudan.edu.cn yuebin@fudan.edu.cn.
Jining ShangDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University Shanghai 200438 China heyonghe@fudan.edu.cn yuebin@fudan.edu.cn.
Tatchamapan YoskamtornDepartment of Chemistry, University of Oxford Oxford OX1 3QR UK edman.tsang@chem.ox.ac.uk.
Xuelei PanDepartment of Chemistry, University of Oxford Oxford OX1 3QR UK edman.tsang@chem.ox.ac.uk.ORCID https://orcid.org/0000-0002-8317-2080
Yiyang LiDepartment of Chemistry, University of Oxford Oxford OX1 3QR UK edman.tsang@chem.ox.ac.uk.ORCID https://orcid.org/0000-0002-9278-7386
Guangchao LiDepartment of Chemistry, University of Oxford Oxford OX1 3QR UK edman.tsang@chem.ox.ac.uk.ORCID https://orcid.org/0000-0001-7521-8336
Tai-Sing WuNational Synchrotron Radiation Research Center 101 Hsin-Ann Road Hsinchu 30076 Taiwan.
Yun-Liang SooNational Synchrotron Radiation Research Center 101 Hsin-Ann Road Hsinchu 30076 Taiwan.ORCID https://orcid.org/0000-0002-1683-3141
Heyong HeDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University Shanghai 200438 China heyonghe@fudan.edu.cn yuebin@fudan.edu.cn.ORCID https://orcid.org/0000-0002-1781-6255
Bin YueDepartment of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University Shanghai 200438 China heyonghe@fudan.edu.cn yuebin@fudan.edu.cn.ORCID https://orcid.org/0000-0001-7935-0684
Shik Chi Edman TsangDepartment of Chemistry, University of Oxford Oxford OX1 3QR UK edman.tsang@chem.ox.ac.uk.ORCID https://orcid.org/0000-0002-8796-3146

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The development of new recyclable and inexpensive electrochemically active species for water oxidation catalysis is the most crucial step for future utilization of renewables. Particularly, transition metal complexes containing internal multiple, cooperative metal centers to couple with redox catalysts in the inorganic Keggin-type polyoxometalate (POM) framework at high potential or under extreme pH conditions would be promising candidates. However, most reported Ni-containing POMs have been highly unstable towards hydrolytic decomposition, which precludes them from application as water oxidation catalysts (WOCs). Here, we have prepared new tri-Ni-containing POMs with variable oxidation states by charge tailored synthetic strategies for the first time and developed them as recyclable POMs for water oxidation catalysts. In addition, by implanting corresponding POM anions into the positively charged MIL-101(Cr) metal-organic framework (MOF), the entrapped Ni

Identifiers

PMID38903226
PMCPMC11186315

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