Evidence map›Paper›PMID 38903207›Full record

ArticleChemical science2024

The importance of understanding (pre)catalyst activation in versatile C-H bond functionalisations catalysed by [Mn

Jonathan B Eastwood, Thomas J Burden, L Anders Hammarback, Chris Horbaczewskyj, Theo F N Tanner, Ian P Clark, Gregory Greetham, Michael Towrie, Ian J S Fairlamb, Jason M Lynam

Abstract read
In one paragraph

Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Jonathan B EastwoodDepartment of Chemistry, University of York York YO10 5DD UK ian.fairlamb@york.ac.uk jason.lynam@york.ac.uk.
Thomas J BurdenDepartment of Chemistry, University of York York YO10 5DD UK ian.fairlamb@york.ac.uk jason.lynam@york.ac.uk.ORCID https://orcid.org/0000-0001-9418-686X
L Anders HammarbackDepartment of Chemistry, University of York York YO10 5DD UK ian.fairlamb@york.ac.uk jason.lynam@york.ac.uk.
Chris HorbaczewskyjDepartment of Chemistry, University of York York YO10 5DD UK ian.fairlamb@york.ac.uk jason.lynam@york.ac.uk.
Theo F N TannerDepartment of Chemistry, University of York York YO10 5DD UK ian.fairlamb@york.ac.uk jason.lynam@york.ac.uk.
Ian P ClarkCentral Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory Harwell Campus Didcot Oxfordshire OX11 0QX UK.
Gregory GreethamCentral Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory Harwell Campus Didcot Oxfordshire OX11 0QX UK.
Michael TowrieCentral Laser Facility, Research Complex at Harwell, STFC Rutherford Appleton Laboratory Harwell Campus Didcot Oxfordshire OX11 0QX UK.
Ian J S FairlambDepartment of Chemistry, University of York York YO10 5DD UK ian.fairlamb@york.ac.uk jason.lynam@york.ac.uk.ORCID https://orcid.org/0000-0002-7555-2761
Jason M LynamDepartment of Chemistry, University of York York YO10 5DD UK ian.fairlamb@york.ac.uk jason.lynam@york.ac.uk.ORCID https://orcid.org/0000-0003-0103-9479

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Mn-catalysed reactions offer great potential in synthetic organic and organometallic chemistry and the success of Mn carbonyl complexes as (pre)catalysts hinges on their stabilisation by strong field ligands enabling Mn(i)-based, redox neutral, catalytic cycles. The mechanistic processes underpinning the activation of the ubiquitous Mn(0) (pre)catalyst [Mn

Identifiers

PMID38903207
PMCPMC11186345

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.