ArticleInorganic chemistry2024
The Chlorido-Bismuth Dication: A Potent Lewis Acid Captured in a Hepta-Coordinate Species with a Stereochemically Active Lone Pair.
Article in Inorganic chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.
What it found
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Who cites it
4 citing papers in PubMed.
- Trifluoromethylbismuth dications: pronounced parallel substrate activation, Lewis superacidity, and catalytic application.Chemical science · 2026Article
- Alkyl Bismuth Cations: Synthesis, Characterization, and Application as Z-Type Ligands.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- The Methylbismuth Dication: Pentagonal Pyramidal Coordination and Ligand-Induced Lewis Superacidity.Angewandte Chemie (International ed. in English) · 2026Article
- Bismuth Meets Olefins: Ethylene Activation and Reversible Alkene Insertion into Bi─N Bonds.Angewandte Chemie (International ed. in English) · 2025Article
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Authors and funding
3 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The stabilization of simple, highly reactive cationic species in molecular complexes represents an important strategy to isolate and characterize compounds with uncommon or even unprecedented structural motifs and properties. Here we report the synthesis, isolation, and full characterization of chlorido-bismuth dications, stabilized only by monodentate dimethylsulfoxide (dmso) ligands: [BiCl(dmso)
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Registered trials
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