ArticleChemical science2024
Neutral inverse-sandwich rare-earth metal complexes of the benzene tetraanion.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. An erratum has been issued. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Synthesis of rare-earth borolide sandwich complexes by multi-electron borole reduction.Chemical science · 2026Article
- Stabilization of the Benzene Radical Trianion in an Inverse-Sandwich Yttrium Complex.Angewandte Chemie (International ed. in English) · 2026Article
- Syntheses and Reactivity of Yb and Sm Inverse Sandwich Arene Complexes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- ηJournal of the American Chemical Society · 2025Article
- Rare earth benzene tetraanion-bridged amidinate complexes.Chemical science · 2025Article
- Four-electron reduction of benzene by a samarium(II)-alkyl without the addition of external reducing agents.Nature chemistry · 2025Article
- Linear Inverse Sandwich Complexes of Tetraanionic Benzene Stabilized by Covalent δ-Bonding with Late Lanthanides.Journal of the American Chemical Society · 2024Article
Corrections and comments
- Erratum issued
Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Rare-earth metal complexes of the parent benzene tetraanion and neutral inverse-sandwich rare-earth metal arene complexes have remained elusive. Here, we report the first neutral inverse-sandwich rare-earth metal complexes of the parent benzene tetraanion supported by a monoanionic β-diketiminate (BDI) ligand. Reduction of the trivalent rare-earth metal diiodide precursors (BDI)MI
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