ArticleEnergy & environmental science2024
Robust battery interphases from dilute fluorinated cations.
Article in Energy & environmental science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- Tailoring the Electric Double Layer for Advanced Rechargeable Batteries: Mechanisms, Strategies, and Outlook.Angewandte Chemie (International ed. in English) · 2026Review
- Dual-additive enabled inorganic-rich solid electrolyte interphase for high-rate lithium negative electrodes.Nature communications · 2026Article
- Real-Time Investigation of Interfacial Evolution in Electrochemical Energy Storage Systems via EQCM.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Review
- Towards practical aqueous zinc metal pouch cell batteries via weakly bound water-mediated shear-thickening electrolyte.Nature communications · 2026Article
- Design of an LiF-rich interface layer using high-concentration fluoroethylene carbonate and lithium bis(fluorosulfonyl)imide (LiFSI) to stabilize Li metal batteries.RSC advances · 2024Article
Corrections and comments
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Authors and funding
12 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Controlling solid electrolyte interphase (SEI) in batteries is crucial for their efficient cycling. Herein, we demonstrate an approach to enable robust battery performance that does not rely on high fractions of fluorinated species in electrolytes, thus substantially decreasing the environmental footprint and cost of high-energy batteries. In this approach, we use very low fractions of readily reducible fluorinated cations in electrolyte (∼0.1 wt%) and employ electrostatic attraction to generate a substantial population of these cations at the anode surface. As a result, we can form a robust fluorine-rich SEI that allows for dendrite-free deposition of dense Li and stable cycling of Li-metal full cells with high-voltage cathodes. Our approach represents a general strategy for delivering desired chemical species to battery anodes through electrostatic attraction while using minute amounts of additive.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.