Evidence map›Paper›PMID 38897990›Full record

ArticleNature communications2024

Bulk-suppressed and surface-sensitive Raman scattering by transferable plasmonic membranes with irregular slot-shaped nanopores.

Roman M Wyss, Günter Kewes, Pietro Marabotti, Stefan M Koepfli, Karl-Philipp Schlichting, Markus Parzefall, Eric Bonvin, Martin F Sarott, Morgan Trassin, Maximilian Oezkent and 11 more

Abstract read
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Ru/RuOAngewandte Chemie (International ed. in English) · 2026
    Article
  3. MOAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026
    Article
  4. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

21 authors.

Roman M WyssInstitut für Physik und IRIS Adlershof, Humboldt-Universität zu Berlin, 12489, Berlin, Germany.ORCID http://orcid.org/0000-0001-5246-2096
Günter KewesInstitut für Physik und IRIS Adlershof, Humboldt-Universität zu Berlin, 12489, Berlin, Germany.
Pietro MarabottiInstitut für Physik und IRIS Adlershof, Humboldt-Universität zu Berlin, 12489, Berlin, Germany.ORCID http://orcid.org/0000-0003-3451-845X
Stefan M KoepfliInstitute of Electromagnetic Fields (IEF), ETH Zürich, 8092 Zürich, Switzerland.
Karl-Philipp SchlichtingLaboratory of Thermodynamics in Emerging Technologies Department of Mechanical and Process Engineering, ETH Zürich, 8092 Zürich, Switzerland.
Markus ParzefallPhotonics Lab, ETH Zürich, 8093 Zürich, Switzerland.ORCID http://orcid.org/0000-0003-2930-6698
Eric BonvinPhotonics Lab, ETH Zürich, 8093 Zürich, Switzerland.
Martin F SarottDepartment of Materials, ETH Zürich, 8093 Zürich, Switzerland.ORCID http://orcid.org/0000-0001-9660-6346
Morgan TrassinDepartment of Materials, ETH Zürich, 8093 Zürich, Switzerland.ORCID http://orcid.org/0000-0002-0240-0257
Maximilian OezkentLeibniz-Institut für Kristallzüchtung, 12489, Berlin, Germany.ORCID http://orcid.org/0000-0001-6435-2599
Chen-Hsun LuLeibniz-Institut für Kristallzüchtung, 12489, Berlin, Germany.ORCID http://orcid.org/0000-0002-2832-2322
Kevin-P GradwohlLeibniz-Institut für Kristallzüchtung, 12489, Berlin, Germany.ORCID http://orcid.org/0000-0003-1841-0289
Thomas PerraultInstitut des Molécules et Matériaux du Mans, UMR 6283 CNRS, Le Mans Université, 72085, Le Mans, France.ORCID http://orcid.org/0000-0001-8481-5124
Lala HabibovaInstitut für Physik und IRIS Adlershof, Humboldt-Universität zu Berlin, 12489, Berlin, Germany.
Giorgia MarcelliInstitut für Physik und IRIS Adlershof, Humboldt-Universität zu Berlin, 12489, Berlin, Germany.
Marcela GiraldoDepartment of Materials, ETH Zürich, 8093 Zürich, Switzerland.
Jan VermantSoft Materials, Department of Materials, ETH Zürich, 8093 Zürich, Switzerland.ORCID http://orcid.org/0000-0002-0352-0656
Lukas NovotnyPhotonics Lab, ETH Zürich, 8093 Zürich, Switzerland.ORCID http://orcid.org/0000-0002-9970-8345
Martin FrimmerPhotonics Lab, ETH Zürich, 8093 Zürich, Switzerland.
Mads C WeberInstitut des Molécules et Matériaux du Mans, UMR 6283 CNRS, Le Mans Université, 72085, Le Mans, France.ORCID http://orcid.org/0000-0002-8837-145X
Sebastian HeegInstitut für Physik und IRIS Adlershof, Humboldt-Universität zu Berlin, 12489, Berlin, Germany. sebastian.heeg@physik.hu-berlin.de.ORCID http://orcid.org/0000-0002-6485-3083

Funding

Deutsche Forschungsgemeinschaft (German Research Foundation) 433878606Einstein Stiftung Berlin (Einstein Foundation Berlin) IPF-2022-727
6 · The paper itself

Abstract

Raman spectroscopy enables the non-destructive characterization of chemical composition, crystallinity, defects, or strain in countless materials. However, the Raman response of surfaces or thin films is often weak and obscured by dominant bulk signals. Here we overcome this limitation by placing a transferable porous gold membrane, (PAuM) on the surface of interest. Slot-shaped nanopores in the membrane act as plasmonic antennas and enhance the Raman response of the surface or thin film underneath. Simultaneously, the PAuM suppresses the penetration of the excitation laser into the bulk, efficiently blocking its Raman signal. Using graphene as a model surface, we show that this method increases the surface-to-bulk Raman signal ratio by three orders of magnitude. We find that 90% of the Raman enhancement occurs within the top 2.5 nm of the material, demonstrating truly surface-sensitive Raman scattering. To validate our approach, we quantify the strain in a 12.5 nm thin Silicon film and analyze the surface of a LaNiO

Identifiers

PMID38897990
PMCPMC11187206

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.