Evidence map›Paper›PMID 38875288›Full record

ArticleChemSusChem2024

Diarylformamides as a Safe Reservoir and Room Temperature Source of Ultra-Pure CO in the Context of a 'Green' rWGS Reaction.

Royel Hurtado, Lisha Lou, Lukas Klerner, Iman Dindarloo Inaloo, Frank W Heineman, Sjoerd Harder, Günter Schmid, Romano Dorta

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in ChemSusChem, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

Royel HurtadoDepartment of Chemistry and Pharmacy, Chair of Inorganic and General Chemistry and Chair of Inorganic and Organometallic Chemistry, Friedrich Alexander Universität Erlangen - Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.
Lisha LouDepartment of Chemistry and Pharmacy, Chair of Inorganic and General Chemistry and Chair of Inorganic and Organometallic Chemistry, Friedrich Alexander Universität Erlangen - Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.
Lukas KlernerDepartment of Chemistry and Pharmacy, Chair of Inorganic and General Chemistry and Chair of Inorganic and Organometallic Chemistry, Friedrich Alexander Universität Erlangen - Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.
Iman Dindarloo InalooDepartment of Chemistry and Pharmacy, Chair of Inorganic and General Chemistry and Chair of Inorganic and Organometallic Chemistry, Friedrich Alexander Universität Erlangen - Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.
Frank W HeinemanDepartment of Chemistry and Pharmacy, Chair of Inorganic and General Chemistry and Chair of Inorganic and Organometallic Chemistry, Friedrich Alexander Universität Erlangen - Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.
Sjoerd HarderDepartment of Chemistry and Pharmacy, Chair of Inorganic and General Chemistry and Chair of Inorganic and Organometallic Chemistry, Friedrich Alexander Universität Erlangen - Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.
Günter SchmidSiemens Energy Global GmbH & Co. KG, New Energy Business - Technology & Products, Freyeslebenstraße 1, 91058, Erlangen, Germany.
Romano DortaDepartment of Chemistry and Pharmacy, Chair of Inorganic and General Chemistry and Chair of Inorganic and Organometallic Chemistry, Friedrich Alexander Universität Erlangen - Nürnberg, Egerlandstraße 1, 91058, Erlangen, Germany.ORCID https://orcid.org/0000-0001-5986-9729

Funding

Bundesministerium für Bildung und Forschung DERIEL-03HY122
6 · The paper itself

Abstract

Diphenylformamide 1 and bisformamide 9 are shown to be safe reservoirs and sources of CO. Their perfectly selective decarbonylations are achieved in solution at room temperature with potassium and cesium diarylamide catalysts. 1 is obtained in excellent yields directly from triethylammonium formate, which may be the product of CO

Indexed as

catalytic decarbonylationLow-temperature rWGSN-formylationN,N-diarylformamidesultra-pure CO

Identifiers

PMID38875288
PMCPMC11587692

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.