ArticleChemical science2024
A nine-ring fused terrylene diimide exhibits switching between red TADF and near-IR room temperature phosphorescence.
Article in Chemical science, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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Who cites it
1 citing paper in PubMed.
- Configuration-packing synergy enabling integrated crystalline-state RTP and amorphous-state TADF.Beilstein journal of organic chemistry · 2026Article
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8 authors.
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Abstract
Herein, we report the first example of a terrylene diimide derivative that switches emission between thermally activated delayed fluorescence (TADF) and room temperature phosphorescence (RTP) in the red region. By design, the molecule TDI-cDBT boasts a symmetrical, consecutively fused nine-ring motif with a kite-like structure. The rigid core formed by the annulated dibenzothiophene moiety favoured efficient intersystem crossing and yielded a narrow-band emission with a full-width half maxima (FWHM) of 0.09 eV, along with high colour purity. A small Δ
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