ArticleNature communications2024
Micro-optical elements from optical-quality ZIF-62 hybrid glasses by hot imprinting.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
What it found
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The trial behind it
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Who cites it
9 citing papers in PubMed.
- Glass formation of metal organic-inorganic complexes.National science review · 2026Article
- Melt-sintering of MOF glass-2D nanosheet composites for enhanced processability and gas separation performance.Chemical science · 2026Article
- Tailoring the Melting and Glass Transition Behavior of Zeolitic Imidazolate Frameworks via Ammonium Halide Salts.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- A Dual-Role Amphiphilic Photosensitizer: Enhancing Structural Uniformity and Optical Properties of Langmuir Monolayers.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Effect of Ligand Substitution on the Formation of the Meltable Fe-ZIF.Materials (Basel, Switzerland) · 2026Article
- White-Light Emission in Zeolitic Imidazolate Framework Glasses.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Unlocking large-area free-standing MOF-glasses for molecular sieving gas separation membranes.Nature communications · 2026Article
- Entropy-mediated solidification stabilizes and enhances energetic release in amorphous energetic materials.Nature communications · 2026Article
- Photonics on a Budget: Low-Cost Polymer Sensors for a Smarter World.Micromachines · 2025Review
Corrections and comments
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Authors and funding
10 authors.
Funding
Abstract
Hybrid glasses derived from meltable metal-organic frameworks (MOFs) promise to combine the intriguing properties of MOFs with the universal processing ability of glasses. However, the shaping of hybrid glasses in their liquid state - in analogy to conventional glass processing - has been elusive thus far. Here, we present optical-quality glasses derived from the zeolitic imidazole framework ZIF-62 in the form of cm-scale objects. These allow for in-depth studies of optical transparency and refraction across the ultraviolet to near-infrared spectral range. Fundamental viscosity data are reported using a ball penetration technique, and subsequently employed to demonstrate the fabrication of micro-optical devices by thermal imprinting. Using 3D-printed fused silica templates, we show that concave as well as convex lens structures can be obtained at high precision by remelting the glass without trading-off on material quality. This enables multifunctional micro-optical devices combining the gas uptake and permeation ability of MOFs with the optical functionality of glass. As an example, we demonstrate the reversible change of optical refraction upon the incorporation of volatile guest molecules.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.