ReviewACS catalysis2024
Mechanisms of Photoredox Catalysis Featuring Nickel-Bipyridine Complexes.
Review in ACS catalysis, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
23 citing papers in PubMed.
- Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Electronic effects on the stability of heteroleptic nickel(II) complexes with aromatic and aliphatic ligands.Journal of molecular modeling · 2026Article
- Recyclable dual Z-scheme perovskite/g-CNature communications · 2026Article
- Base Metal Photocatalysts: A Bright Future in Photoredox Catalysis?Organometallics · 2026Article
- Arylhydrazines: Convenient Homogeneous Reductants for Scalable Cross-Coupling.Angewandte Chemie (International ed. in English) · 2026Article
- Triplet Energy Transfer as a Handle to Tune 1,2-Dialkyldiazene Fragmentation in Radical C(spJournal of the American Chemical Society · 2026Article
- Multireference Modeling Reveals the Origins of L‑Edge X‑ray Absorption Features in Photoredox-Active Nickel Complexes.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Stereoselective vicinal C(sp³)-C bond formation via metallaphotoredox 1,2-difunctionalization of internal alkenes.Nature communications · 2026Article
- Ultrafast Population and Structural Dynamics of a Ni-Bipyridine Photoredox Catalyst Reveal a Significant Deactivation Pathway.The journal of physical chemistry letters · 2026Article
- Decoding the Nested, Multicycle Mechanism of Ni-Catalyzed Redox-Neutral Cross-Coupling through Temperature Scanning Reaction Calorimetry.Journal of the American Chemical Society · 2026Article
- Harnessing Photochemistry in Natural Product Synthesis: From Strategy to Applications.Journal of natural products · 2025Review
- Development, Application, and Mechanistic Interrogation of a Dual Ni Catalysis Approach to Photoredox-Based C(spJournal of the American Chemical Society · 2025Article
- Direct Synthesis of α‑Amino Ketones via Photochemical Nickel-Catalyzed Acyl-Aryl Cross-Coupling.ACS omega · 2025Article
- Generalizing Vinyl Halide Cross-Coupling Reactions with Photoredox and Photoredox/Nickel Dual Catalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Reactivity Studies of Bipyridine-Ligated Nickel(I) and Nickel(0) Complexes Inform the Mechanism in Modern Cross-Coupling Reactions.Journal of the American Chemical Society · 2025Article
- Article
- Photolytic activation of NiNature communications · 2025Article
- Indole Photocatalysts and Secondary Amine Ligands Enable Nickel-Photoredox C(spACS catalysis · 2025Article
- Nickel-Mediated Radical Capture: Evidence for a Concerted Inner-Sphere Mechanism.Journal of the American Chemical Society · 2025Article
- Stereoretentive radical cross-coupling.Nature · 2025Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Metallaphotoredox catalysis can unlock useful pathways for transforming organic reactants into desirable products, largely due to the conversion of photon energy into chemical potential to drive redox and bond transformation processes. Despite the importance of these processes for cross-coupling reactions and other transformations, their mechanistic details are only superficially understood. In this review, we have provided a detailed summary of various photoredox mechanisms that have been proposed to date for Ni-bipyridine (bpy) complexes, focusing separately on photosensitized and direct excitation reaction processes. By highlighting multiple bond transformation pathways and key findings, we depict how photoredox reaction mechanisms, which ultimately define substrate scope, are themselves defined by the ground- and excited-state geometric and electronic structures of key Ni-based intermediates. We further identify knowledge gaps to motivate future mechanistic studies and the development of synergistic research approaches spanning the physical, organic, and inorganic chemistry communities.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.