ArticleJournal of the American Chemical Society2024
Self-Assembly of Chiral Porous Metal-Organic Polyhedra from Trianglsalen Macrocycles.
Article in Journal of the American Chemical Society, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 9 papers.
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Who cites it
9 citing papers in PubMed.
- Phase-dependent responsiveness in soft porous crystals assembled from flexible metal-organic cages.Chemical science · 2026Article
- Adaptive Cavity-Enabled Crystalline Chirality in Nanocarbon Cages.Angewandte Chemie (International ed. in English) · 2026Article
- Mandelic Acid-Mediated Enantiomeric Enrichment of a Resorcinarene-Based Dissymmetric Coordination Capsule.Chemistry, an Asian journal · 2026Article
- A self-assembled macrocycle with a non-closed structure for hierarchically upgraded self-assembly.Chemical science · 2026Article
- Light-Driven Lithium Extraction from Mixtures of Alkali Cations Using an Azobipyridine Ligand.Journal of the American Chemical Society · 2025Article
- Paramagnetic Cage-Type Co(II) Complexes of Chiral Macrocycles: Enantio- and Size-Selective Binding of Guest Molecules.Inorganic chemistry · 2025Article
- Thio-modified trianglimines, a novel group of chiral macrocyclic compounds of high structural dynamics.Scientific reports · 2025Article
- Intricate Low-Symmetry AgJournal of the American Chemical Society · 2024Article
- Double-Bridging Increases the Stability of Zinc(II) Metal-Organic Cages.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Metal-organic polyhedra (MOPs) can exhibit tunable porosity and functionality, suggesting potential for applications such as molecular separations. MOPs are typically constructed by the bottom-up multicomponent self-assembly of organic ligands and metal ions, and the final functionality can be hard to program. Here, we used trianglsalen macrocycles as preorganized building blocks to assemble octahedral-shaped MOPs. The resultant MOPs inherit most of the preorganized properties of the macrocyclic ligands, including their well-defined cavities and chirality. As a result, the porosity in the MOPs could be tuned by modifying the structure of the macrocycle building blocks. Using this strategy, we could systematically enlarge the size of the MOPs from 26.3 to 32.1 Å by increasing the macrocycle size. The family of MOPs shows experimental surface areas of up to 820 m
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.