Evidence map›Paper›PMID 38855332›Full record

ReviewACS organic & inorganic Au2024

Recent Advances on the Catalytic Asymmetric Allylic α-Alkylation of Carbonyl Derivatives Using Free Allylic Alcohols.

Diego A Alonso, Beatriz Maciá, Isidro M Pastor, Alejandro Baeza

Abstract readReview
In one paragraph

Review in ACS organic & inorganic Au, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Copper(I)-Catalyzed Enantioselective α-Alkylation of 2-Acylimidazoles.Journal of the American Chemical Society · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Diego A AlonsoInstituto de Síntesis Orgánica, and Dpto. de Química Orgánica, Universidad de Alicante, Apdo. 99, 03080 Alicante, Spain.ORCID https://orcid.org/0000-0002-9069-1188
Beatriz MaciáDepartment of Natural Sciences, Manchester Metropolitan University, Oxford Road, Manchester M1 5GD, United Kingdom.
Isidro M PastorInstituto de Síntesis Orgánica, and Dpto. de Química Orgánica, Universidad de Alicante, Apdo. 99, 03080 Alicante, Spain.ORCID https://orcid.org/0000-0002-8271-0641
Alejandro BaezaInstituto de Síntesis Orgánica, and Dpto. de Química Orgánica, Universidad de Alicante, Apdo. 99, 03080 Alicante, Spain.ORCID https://orcid.org/0000-0002-6230-1162

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

During the last years, the development of more sustainable and straightforward methodologies to minimize the generation of waste organic substances has acquired high importance within synthetic organic chemistry. Therefore, it is not surprising that many efforts are devoted to ameliorating already well-known successful methodologies, that is, the case of the asymmetric allylic allylation reaction of carbonyl compounds. The use of free alcohols as alkylating agents in this transformation represents a step forward in this sense since it minimizes waste production and the substrate manipulation. In this review, we aim to gather the most recent methodologies describing this strategy by paying special attention to the reaction mechanisms, as well as their synthetic applications.

Identifiers

PMID38855332
PMCPMC11157516

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.