Evidence map›Paper›PMID 38852174›Full record

ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2024

Photochemical Action Plots Map Orthogonal Reactivity in Photochemical Release Systems.

Rita T Michenfelder, Fred Pashley-Johnson, Viktor Guschin, Laura Delafresnaye, Vinh X Truong, Hans-Achim Wagenknecht, Christopher Barner-Kowollik

Abstract read
In one paragraph

Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Article
  3. Precision Photochemistry: Every Photon Counts.Angewandte Chemie (International ed. in English) · 2025
    Article
  4. Article
  5. Photochemical Action Plots Map Orthogonal Reactivity in Photochemical Release Systems.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Rita T MichenfelderSchool of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George St, Brisbane, QLD, 4000, Australia.
Fred Pashley-JohnsonSchool of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George St, Brisbane, QLD, 4000, Australia.ORCID https://orcid.org/0000-0002-9920-8682
Viktor GuschinInstitute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.
Laura DelafresnayeSchool of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George St, Brisbane, QLD, 4000, Australia.ORCID https://orcid.org/0000-0002-4657-9359
Vinh X TruongInstitute of Sustainability for Chemicals, Energy and Environment (ISCE2), Agency for Science, Technology and Research (A*STAR), 1 Pesek Round, Jurong Island, Singapore, 627833, Republic of Singapore.
Hans-Achim WagenknechtInstitute of Organic Chemistry, Karlsruhe Institute of Technology (KIT), Fritz-Haber-Weg 6, 76131, Karlsruhe, Germany.
Christopher Barner-KowollikSchool of Chemistry and Physics, Centre for Materials Science, Queensland University of Technology (QUT), 2 George St, Brisbane, QLD, 4000, Australia.ORCID https://orcid.org/0000-0002-6745-0570

Funding

Australian Research CouncilDeutsche ForschungsgemeinschaftQUT's Centre for Materials ScienceQUT's Research Portfolio
6 · The paper itself

Abstract

The wavelength-by-wavelength resolved photoreactivity of two photo-caged carboxylic acids, i. e. 7-(diethylamino)-coumarin- and 3-perylene-modified substrates, is investigated via photochemical action plots. The observed wavelength-dependent reactivity of the chromophores is contrasted with their absorption profile. The photochemical action plots reveal a remarkable mismatch between the maximum reactivity and the absorbance. Through the action plot data, the study is able to uncover photochemical reactivity maxima at longer and shorter wavelengths, where the molar absorptivity of the chromophores is strongly reduced. Finally, the laser experiments are translated to light emitting diode (LED) irradiation and show efficient visible-light-induced release in a near fully wavelength-orthogonal, sequence-independent fashion (λ

Indexed as

photochemical action plotsprecision photochemistrywavelength orthogonal release systems

Identifiers

PMID38852174
PMCPMC11304248

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.