ArticleNature communications2024
Closed-loop recycling of tough epoxy supramolecular thermosets constructed with hyperbranched topological structure.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
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The trial behind it
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Who cites it
15 citing papers in PubMed.
- Role of Acid Structure in Structure-Property Relationships of Reprocessable Epoxidized Soybean Oil Thermosetting Networks.Polymers · 2026Article
- Kinetically inert covalent adaptable networks enable holistic resource recovery from high-performance printed circuit boards.Nature communications · 2026Article
- Supramolecular Nanoclusters Enable High-Performance and Recyclable Epoxy Resins.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Mechanical and Dielectric Properties of Epoxy Resin Toughened by a Hydroxyl-Terminated Hyperbranched Polymer.Polymers · 2026Article
- Shear-Stiffening Damping Ionogels Enabled by the Synergy of Dynamic Bonds and Steric Hindrance.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- A Fully Bio-Based Elastomer with Ultrahigh Lignin Content and Performance Rivaling Nitrile Rubber.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Article
- Minimal N-hydroxyphthalimide-urethane bonds enable superior thermomechanical stability for covalent adaptable networks.Nature communications · 2026Article
- Strong, Recyclable, Bio-Based Vitrimers by Tailored Rigid-Flexible Structures for Advanced Carbon Fiber-Reinforced Polymers.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Delayed crystallization response-inspired waterborne polyurethane with high performance.Nature communications · 2025Article
- Liquid Metal-Vitrimer Conductive Composite for Recyclable and Resilient Electronics.Advanced materials (Deerfield Beach, Fla.) · 2025Article
- Engineering of Multi-Dynamic Bonds Toward Room-Temperature Self-Healing Epoxy/MXene Adaptable Network with Record-High Toughness.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Healable Glassy Metallosupramolecular Polymers.ACS macro letters · 2025Article
- Sustainable Development of High-performance Poly(ester-imine) Biobased Thermosets.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Article
- Processable Bio-Based Polybenzoxazine with Tunable Toughness and Dielectric Properties.Research (Washington, D.C.) · 2025Article
Corrections and comments
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Authors and funding
9 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The regulation of topological structure of covalent adaptable networks (CANs) remains a challenge for epoxy CANs. Here, we report a strategy to develop strong and tough epoxy supramolecular thermosets with rapid reprocessability and room-temperature closed-loop recyclability. These thermosets were constructed from vanillin-based hyperbranched epoxy resin (VanEHBP) through the introduction of intermolecular hydrogen bonds and dual dynamic covalent bonds, as well as the formation of intramolecular and intermolecular cavities. The supramolecular structures confer remarkable energy dissipation capability of thermosets, leading to high toughness and strength. Due to the dynamic imine exchange and reversible noncovalent crosslinks, the thermosets can be rapidly and effectively reprocessed at 120 °C within 30 s. Importantly, the thermosets can be efficiently depolymerized at room temperature, and the recovered materials retain the structural integrity and mechanical properties of the original samples. This strategy may be employed to design tough, closed-loop recyclable epoxy thermosets for practical applications.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.