Evidence map›Paper›PMID 38844481›Full record

ArticleNature communications2024

Collective chiroptical activity through the interplay of excitonic and charge-transfer effects in localized plasmonic fields.

Huacheng Li, Xin Xu, Rongcheng Guan, Artur Movsesyan, Zhenni Lu, Qiliang Xu, Ziyun Jiang, Yurong Yang, Majid Khan, Jin Wen and 10 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

20 authors.

Huacheng Li *State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.
Xin Xu *State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.
Rongcheng GuanState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.
Artur MovsesyanInstitute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, 610054, Chengdu, China.ORCID http://orcid.org/0000-0002-5425-7747
Zhenni LuState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.
Qiliang XuState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.
Ziyun JiangState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.
Yurong YangState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.
Majid KhanState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.
Jin WenState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.ORCID http://orcid.org/0000-0001-6136-8771
Hongwei WuState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.
Santiago de la MoyaDepartamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, Ciudad Universitaria s/n, 28040, Madrid, Spain.ORCID http://orcid.org/0000-0002-7406-909X
Gil MarkovichSchool of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv, 69978, Israel.
Huatian HuCenter for Biomolecular Nanotechnologies, Istituto Italiano di Tecnologia, Via Barsanti 14, Arnesano, 73010, LE, Italy.
Zhiming WangInstitute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, 610054, Chengdu, China.
Qiang GuoState Key Laboratory of Protein and Plant Gene Research, Center for Life Sciences, Academy for Advanced Interdisciplinary Studies, School of Life Sciences, Peking University, 100871, Beijing, China.ORCID http://orcid.org/0000-0003-3520-5439
Tao YiState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China.ORCID http://orcid.org/0000-0002-3309-8556
Alexander O GovorovInstitute of Fundamental and Frontier Sciences, University of Electronic Science and Technology of China, 610054, Chengdu, China. govorov@ohio.edu.ORCID http://orcid.org/0000-0003-1316-6758
Zhiyong TangCAS Key Laboratory of Nanosystem and Hierarchical Fabrication & CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, 100190, Beijing, China.ORCID http://orcid.org/0000-0003-0610-0064
Xiang LanState Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, 201620, Shanghai, China. xlan@dhu.edu.cn.ORCID http://orcid.org/0000-0003-4845-9956

Funding

National Natural Science Foundation of China (National Science Foundation of China) 22372031
6 · The paper itself

Abstract

The collective light-matter interaction of chiral supramolecular aggregates or molecular ensembles with confined light fields remains a mystery beyond the current theoretical description. Here, we programmably and accurately build models of chiral plasmonic complexes, aiming to uncover the entangled effects of excitonic correlations, intra- and intermolecular charge transfer, and localized surface plasmon resonances. The intricate interplay of multiple chirality origins has proven to be strongly dependent on the site-specificity of chiral molecules on plasmonic nanoparticle surfaces spanning the nanometer to sub-nanometer scale. This dependence is manifested as a distinct circular dichroism response that varies in spectral asymmetry/splitting, signal intensity, and internal ratio of intensity. The inhomogeneity of the surface-localized plasmonic field is revealed to affect excitonic and charge-transfer mixed intermolecular couplings, which are inherent to chirality generation and amplification. Our findings contribute to the development of hybrid classical-quantum theoretical frameworks and the harnessing of spin-charge transport for emergent applications.

Identifiers

PMID38844481
PMCPMC11156920

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.