Evidence map›Paper›PMID 38842466›Full record

ReviewChemSusChem2024

Dynamic Covalent Chemistry of Enamine-Ones: Exploring Tunable Reactivity in Vitrimeric Polymers and Covalent Organic Frameworks.

Thaksen Jadhav, Bhausaheb Dhokale, Zeinab M Saeed, Nikos Hadjichristidis, Sharmarke Mohamed

Abstract readReview
In one paragraph

Review in ChemSusChem, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 4 papers.

0numbers the graph read from it
0cells of the map it votes in
4citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

4 citing papers in PubMed.

  1. Article
  2. Review
  3. Review
  4. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Thaksen JadhavDepartment of Chemistry, Green Chemistry & Materials Modelling Laboratory, Khalifa University of Science and Technology, PO Box, Abu Dhabi, 127788, United Arab Emirates.ORCID https://orcid.org/0000-0002-6031-7793
Bhausaheb DhokaleDepartment of Chemistry, Green Chemistry & Materials Modelling Laboratory, Khalifa University of Science and Technology, PO Box, Abu Dhabi, 127788, United Arab Emirates.
Zeinab M SaeedDepartment of Chemistry, Green Chemistry & Materials Modelling Laboratory, Khalifa University of Science and Technology, PO Box, Abu Dhabi, 127788, United Arab Emirates.
Nikos HadjichristidisChemistry Program, KAUST Catalysis Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal, 23955, Saudi Arabia.
Sharmarke MohamedDepartment of Chemistry, Green Chemistry & Materials Modelling Laboratory, Khalifa University of Science and Technology, PO Box, Abu Dhabi, 127788, United Arab Emirates.

Funding

ASPIRE AARE20-259
6 · The paper itself

Abstract

Dynamic covalent chemistry (DCC) has revolutionized the field of polymer science by offering new opportunities for the synthesis, processability, and recyclability of polymers as well as in the development of new materials with interesting properties such as vitrimers and covalent organic frameworks (COFs). Many DCC linkages have been explored for this purpose, but recently, enamine-ones have proven to be promising dynamic linkages because of their facile reversible transamination reactions under thermodynamic control. Their high stability, stimuli-responsive properties, and tunable kinetics make them promising dynamic cross-linkers in network polymers. Given the rapid developments in the field in recent years, this review provides a critical and up-to-date overview of recent developments in enamine-one chemistry, including factors that control their dynamics. The focus of the review will be on the utility of enamine-ones in designing a variety of processable and self-healable polymers with important applications in vitrimers and recyclable closed-loop polymers. The use of enamine-one linkages in crystalline polymers, known as COFs and their applications are also summarized. Finally, we provide an outlook for future developments in this field.

Indexed as

Covalent organic frameworksdynamic covalent chemistryEnamine-onerecyclable polymersvitrimer

Identifiers

PMID38842466
PMCPMC11587689

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.