ArticleScience advances2024
Monodisperse nanosheet mesophases.
Article in Science advances, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Multi-functional photonic crystals of modular nanosheets.Nature communications · 2026Article
- Bridging the Gap between Osmotic and Crystalline Swelling in 2D Layered Materials Using Levitated Droplets.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Liquid-Crystalline Photonic Sandwich: Electroresponsive Colloids of Clay Nanosheets Loading Photofunctional Dyes.Langmuir : the ACS journal of surfaces and colloids · 2024Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Self-assemblies of anisotropic colloidal particles into colloidal liquid crystals and well-defined superlattices are of great interest for hierarchical nanofabrications that are applicable for various functional materials. Inorganic nanosheets obtained by exfoliation of layered crystals have been highlighted as the intriguing colloidal units; however, the size polydispersity of the nanosheets has been preventing precise design of the assembled structures and their functions. Here, we demonstrate that the anionic titanate nanosheets with monodisperse size reversibly form very unusual superstructured mesophases through finely tunable weak attractive interactions between the nanosheets. Transmission electron microscopy, polarizing optical microscopy, small-angle x-ray scattering, and confocal laser scanning microscopy clarified the reversible formation of the mesophases (columnar nanofibers, columnar nematic liquid crystals, and columnar nanofiber bundles) as controlled by counter cations, nanosheet concentration, solvent, and temperature.
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Registered trials
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