ArticleNature communications2024
Picosecond reactions of excited radical ion super-reductants.
Article in Nature communications, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 27 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
27 citing papers in PubMed.
- Mechanistic Diversity in Photoexcited Radical Redox Chemistry: A Critical Evaluation.Angewandte Chemie (International ed. in English) · 2026Review
- Magnetic Electroluminescent response as a predictive indicator of operational lifetime in phosphorescent blue OLEDs.Nature communications · 2026Article
- Photophysics of Doubly Reduced Quinacridone Dyes: Toward Redox Reactivity Activated by Red Light.Artificial photosynthesis (Washington, D.C.) · 2026Article
- Pre-association enables visible-light induced proton-coupled electron-transfer in a titanium-functionalized polyoxotungstate.Chemical science · 2026Article
- Metal-Centered Photoredox Catalysis using d6 Transition Metal-based Chromophores.Accounts of chemical research · 2026Article
- Evidence of static quenching in the photoredox activity of perylene diimide radical anions: implications for consecutive photoinduced electron transfer photocatalysis.Chemical science · 2026Article
- Photocatalytic Controlled Halodefluorination of Perfluoroalkyl Compounds UsingJournal of the American Chemical Society · 2026Article
- Kinetics vs Thermodynamics: Engineering Photoredox Reactivity from an Upper Excited State of FeJournal of the American Chemical Society · 2026Article
- Near-Infrared-Light-Driven Photochemistry and Photocatalysis: Mechanisms, Recent Applications, and Opportunities in Organic Synthesis and Biology.Angewandte Chemie (International ed. in English) · 2026Review
- Mechanistic Design in Photocatalysis.Accounts of chemical research · 2026Article
- Expanding Thermodynamic and Kinetic Frontiers in Molecular Photocatalysis.ACS central science · 2026Review
- Article
- Polymer connectivity governs electrophotocatalytic activity in the solid state.Nature chemistry · 2025Article
- Photoinduced double charge accumulation in a molecular compound.Nature chemistry · 2025Article
- Spin-State and Reorganization Energy Considerations for Metal-Centered Photoredox Catalysis.Journal of the American Chemical Society · 2025Article
- Generalizing Vinyl Halide Cross-Coupling Reactions with Photoredox and Photoredox/Nickel Dual Catalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Rapid Electrochemical Assessment of Excited-State Quenching Dynamics.ACS catalysis · 2025Article
- Counterintuitive Photochemistry of an Isolated Acridinyl Radical: ConPET via Preassembly, Solvated Electrons or a Long-Lived Excited State?Angewandte Chemie (International ed. in English) · 2025Article
- Structural Control of Metal-Centered Excited States in Cobalt(III) Complexes via Bite Angle and π-π Interactions.Journal of the American Chemical Society · 2025Article
- Pushing the Thermodynamic and Kinetic Limits of Near-Infrared Emissive CrJournal of the American Chemical Society · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
Abstract
Classical photochemistry requires nanosecond excited-state lifetimes for diffusion-controlled reactions. Excited radicals with picosecond lifetimes have been implied by numerous photoredox studies, and controversy has arisen as to whether they can actually be catalytically active. We provide direct evidence for the elusive pre-association between radical ions and substrate molecules, enabling photoinduced electron transfer beyond the diffusion limit. A strategy based on two distinct light absorbers, mimicking the natural photosystems I and II, is used to generate excited radicals, unleashing extreme reduction power and activating C(sp
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.